Abstract
ZnO nanoparticles were mixed with low density polyethylene (LDPE) to form nanocomposites. The distribution of ZnO filler particles was controlled by changing the mixing method, and the effects of controlled inhomogeneous distribution on the electrical resistivity were measured. The percolation limit in the composites with controlled inhomogeneity decreased significantly compared to that of the analogous nanocomposites with uniform filler distributions, and the resistivity of the filled composites decreased as a function of applied field strength, exhibiting a nonlinear I–V relationship. The nonlinearity increased with ZnO filler concentration.
Similar content being viewed by others
Reference
Godovsky DY (2000) Adv Polym Sci 153:163
Gleiter H, Weissmüller J, Wollersheim O, Würschum R (2001) Acta Mater 49:737
Brus L (1986) J Phys Chem 90:2555
Henk PO, Kortsen TW, Kvarts T (1999) High Perform Polym 11:281
Ash BJ, Schadler LS, Siegel RW (2002) Mater Lett 55:83
Ng CB, Ash BJ, Schadler LS, Siegel RW (2001) Adv Compos Lett 10:101
Hong JI, Schadler LS, Siegel RW, Mårtensson E (2003) Appl Phys Lett 82:1956
Stauffer D, Aharony A (1991) Introduction to percolation. Theory Taylor & Francis Inc., Washington, DC
Ueki MM, Zanin M (1999) IEEE Trans Dielec Elec Insul 6:876
Coleman JN, Curran S, Dalton AB, Davey AP, McCarthy B, Blau W, Barklie RC (1998) Phys Rev B58:7492
Wycisk R, Poźniak R, Pasternak A (2002) J Electrostat 56:55
Nan CW, Tschöpe A, Holten S, Kliem H, Birringer R (1999) J Appl Phys 85:7735
Hong JI, Cho KS, Chung CI, Schadler LS, Siegel RW (2002) J Mater Res 17:940
Amey WG, Hamburger F (1949) Proc ASTM 49:1079
Acknowledgement
We acknowledge ABB for funding this work and Nanophase Technologies Corporation for donating nanoparticles. This work was supported in part by the Nanoscale Science and Engineering Initiative of the National Science Foundation under NSF Award Number DMR-0117792.
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Hong, J.I., Schadler, L.S., Siegel, R.W. et al. Electrical behavior of low density polyethylene containing an inhomogeneous distribution of ZnO nanoparticles. J Mater Sci 41, 5810–5814 (2006). https://doi.org/10.1007/s10853-006-0331-1
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10853-006-0331-1