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Journal of Materials Science

, Volume 40, Issue 23, pp 6301–6306 | Cite as

A comparative study of the effects of Cu, Rh doping on the microstructure, morphological and optical properties of tin dioxide nanocrystallines

  • C. X. Hu
  • Y. S. Wu
  • H. Y. Wei
  • Y. C. Shi
  • L. L. Wu
Article

Abstract

Based on the method of bridging coordinated precursor, pure and Cu, Rh doped tin oxide have been synthesized in order to investigate the influence of metal doping and multi-metal doping on the microstructure and optical properties of the host material. We attest to the formation of a chain-like precursor by FTIR analysis. All the studied systems were characterized by XRD, TEM/HRTEM and UV-VIS. Although Cu doping has few effects on the microstructure, it improves the optical properties of the host material. However Rh doping can apparently affect both the microstructure and the optical property. In the co-doped system, Cu doping reduces the effectiveness of Rh doping greatly.

Keywords

Oxide Polymer Microstructure Dioxide Optical Property 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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References

  1. 1.
    W. A. BADAWAY, J. Electr. Chem. 281 (1990) 85.Google Scholar
  2. 2.
    N. MANEVA, K. KYNEV, L. GRIGOROV et al., J. Mater. Sci. Lett. 16 (1997) 1037.CrossRefGoogle Scholar
  3. 3.
    J. R. YU, G. Z. HUANG and Y. J. YANG, Sens. Actuat. B 66 (2000) 286.Google Scholar
  4. 4.
    Y. T. LI, C. W. YAN and C. X. HU, Polish J. Chem. 75 (2001) 329.Google Scholar
  5. 5.
    C. X. HU, Z. H. JING and Y. T. LI, J. Qufu Normal University (Natural Science) 26 (2000) 68.Google Scholar
  6. 6.
    C. V. SANTILLI, S. H. PULCINELLI and G. E. S. BRITO, J. Phys. Chem. B 103 (1999) 2660.CrossRefGoogle Scholar
  7. 7.
    E. R. LEITE, J. A. CERRI and E. LONGO et al. J. Eur. Ceram. Soc. 21 (2001) 669.CrossRefGoogle Scholar
  8. 8.
    I. T. WEBER, R. ANDRADE and E. R. LEITE, Sens. Actuat. B 72 (2001) 180.Google Scholar
  9. 9.
    R. MIENTUS and K. ELLMER, Surf. Coat. Technol. 98 (1998) 1267.CrossRefGoogle Scholar
  10. 10.
    Powder Diffraction File, Data Cards, Inorganic Section, JCPDS, Swarthmore, PA, 1987, 21–1250.Google Scholar
  11. 11.
    K. N. YU, Y. XIONG and Y. LIN et al., Phys. Rev. B 55 (1992) 2666.Google Scholar
  12. 12.
    TEM/HRTEM analysis of Cu10 mol% doping SnO2 were performed on 200 Kv JEOL TEM-2010 ARP; TEM/HRTEM analysis of the other three samples were performed on a Philips U-TWIN TEC NAI 20.Google Scholar
  13. 13.
    D. Z. LIAO, Z. Y. ZHANG and Q. H. ZHAO et al., J. Chin. Inorg. Chem. 6 (1990) 193.Google Scholar
  14. 14.
    D. Z. LIAO, J. SHI and Z. H. JIANG et al., J. Chin. Chem. 52 (1994) 171.Google Scholar
  15. 15.
    Sadtler Commercial Spectra, IR Grating, INORGANICS, Vol. 1, Y157 O2Sn.Google Scholar
  16. 16.
    Y. K. KE and H. R. DONG, “The Enchiridion of Analytical Chemistry,” 2nd edn (Chemical Industry Press, Pekin, 1998) p. 933.Google Scholar
  17. 17.
    F. CIRILLI, S. KACIULIS, G. MATTOGNO et al., Thin Solid Films 315 (1998) 310.CrossRefGoogle Scholar

Copyright information

© Springer Science + Business Media, Inc. 2005

Authors and Affiliations

  • C. X. Hu
    • 1
  • Y. S. Wu
    • 2
  • H. Y. Wei
    • 2
  • Y. C. Shi
    • 2
  • L. L. Wu
    • 2
  1. 1.The Editorial Department of Journal (Science and Technology) of Shandong UniversityJinanPeople's Republic of China
  2. 2.School of Materials Science and EngineeringShandong UniversityJinanPeople's Republic of China

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