Advertisement

Journal of Materials Science

, Volume 40, Issue 13, pp 3367–3373 | Cite as

Manifestation of Nd ions on the structure, Raman and IR spectra of (TeO2-MoO-Nd2O3) glasses

  • I. Shaltout
  • Y. BadrEmail author
Article

Abstract

The structure of [80TeO2 + (20–x)MoO + xNd2O3] glasses, with x = 0, 4, 6, 10 and 12 mol%, is studied in this work. Raman scattering in the spectral range (−2000 to 3500 cm−1) and IR absorption spectra have been measured for crystalline TeO2 and glasses, and their assignments were discussed and compared. Many vibrational modes were found active in both Raman and IR and their assignments for crystalline TeO2 and for the glasses were discussed in relation to the tetragonal structure of crystalline α -TeO2. Nd2O3 was found to completely eliminate diffuse scattering and enhance the Raman scattering intensity. Anti-stokes Raman bands in the range −1460 cm− 1 to −1975 cm− 1 were observed for both (30Li2O + 70B2O3+ xNd2O3) glasses and [80TeO2 + (20−x)MoO + xNd2O3] glasses and were attributed to some emission processes due to the doping of the glasses with Nd2O3.

Keywords

Polymer Absorption Spectrum Spectral Range Vibrational Mode Raman Scattering 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

Preview

Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.

References

  1. 1.
    H. NASU, O. MATSUSHITA, K. KAMIYA and H. KUBODERA, J. Non. Cryst. Solids 124 (1990) 275.Google Scholar
  2. 2.
    S. H. KIM, T. YOKA and S. SAKA, J. Amer. Ceram. Soc. 76 (1993) 865.Google Scholar
  3. 3.
    I. V. KITYK, J. KASPERCZYK and K. PLUCINSKI, J. Opt. Soc. America B V16 10 (1999) 1719.Google Scholar
  4. 4.
    H. HIROSHI, I. MICHIHISA and T. YOSHIDA, J. Non. Cryst. Solids 86 (1986) 327.Google Scholar
  5. 5.
    E. F. LAMBSON, G. A. SANDERS, B. BRIDGE and R. A. ELMALLAWANY, J. Non. Cryst. Solids 69 (1984) 117.Google Scholar
  6. 6.
    S. NEOV, E. GREVASSIMOVA and B. SYDZHIMOV, Phys. Status Solidi (a) 76 (1983) 297.Google Scholar
  7. 7.
    Y. DIMITRRIEV, V. DIMITROV and M. ARANUDOV, J. Mat. Sci. 18 (1983) 1353.Google Scholar
  8. 8.
    I. SHALTOUT, YI TANG, R. BRAUNSTEIN and A. M. ABU EL-AZM, J. Phys. Chem. Solids 56 (1995) 141.Google Scholar
  9. 9.
    I. SHALTOUT, YI TANG, R. BRAUNSTEIN and E. E. SHAISHA, J. Phys. Chem. Solids 57 (1996) 1223.Google Scholar
  10. 10.
    I. SHALTOUT, J. Mat. Sci. 35 (2000) 323.Google Scholar
  11. 11.
    M. J. WEBER, J. D. MYERS and D. H. BLACKBURN, J. Appl. Phys. 52 (1981) 2944.Google Scholar
  12. 12.
    S. TANABE, K. HIRAO and N. SOGA, J. Non. Cryst. Solids 122 (1990) 79.Google Scholar
  13. 13.
    H. NII, K. OZAKI, M. HERREN and M. MORITA, J. Lumin. 76/77 (1998) 116.Google Scholar
  14. 14.
    A. MORI, Y. OHISHI and S. SUDO, Electron. Lett 33 (1997) 863.Google Scholar
  15. 15.
    L. L. NEINDRE, SHIBIN JIANG, BOR-CHYUAN HWANG, TABLUO and JASON WATSON, J. Non. Cryst. Solids 255 (1999) 97.Google Scholar
  16. 16.
    K. HIRAO, S. KOSHIMOTO, K. TANAKA, S. TANABE and N. SOGA, J. Non. Cryst. Solids. 139 (1992) 151.Google Scholar
  17. 17.
    J. RULLER and J. SHELBY, J. Phys. Chem. Solids 33 (1992) 177.Google Scholar
  18. 18.
    V. RAVI KUMAR and N. VEERAIAH, J. Phys. Chem. Solids 59 (1998) 91.Google Scholar
  19. 19.
    V. RAVI KUMAR, N. VEERAIAH, B. APPA RAO and S. BHUDDUDU, J. Mat. Sci. 33 (1998) 2659.Google Scholar
  20. 20.
    G. AMARNATH, S. BUDDHUDU and F. G. BRAYANT, J. Lumin. 15 (1991) 17.Google Scholar
  21. 21.
    G. AMARNATH, S. BUDDHUDU and F. G. BRAYANT, J. Non. Cryst. Solids 122 (1990) 86.Google Scholar
  22. 22.
    FABIA C. CASSANJES, YOUNES MESSADDEQ, LUIZ F. C. DE OLIVEIRA, LILIA C. COURROL, LAERCIO GOMES and SIDNEY J. L. RIBEIRO, J. Non. Cryst. Solids 1247 (1999) 58.Google Scholar
  23. 23.
    O. NOGUERA, T. MERLE-MEJEAN, A. P. MIRGORODSKY, M. B. SMIRNOV, P. THOMAS and J. C. CHAMPARNAUD-MESJARD, J. Non. Cryst. Solids 330 (2003) 50.Google Scholar
  24. 24.
    R. A. F. EL-MALLAWANY, “Tellurite Glasses Handbook: Properties and Data, CRC,” Boca Raton, FL, 2002.Google Scholar
  25. 25.
    S. BLANCHANDIN, P. MARCHET, P. THOMAS, J. C. CHAMPARNAUD-MESJARD, B. FRIT and A. CHAGRAOUI, J. Mat. Sci. 34 (1999) 4285.Google Scholar
  26. 26.
    J. C. CHAMPARNAUD-MESJARD, S. BLANCHANDIN, P. THOMAS, A. MIRGORODSKY, T. MERLE-MEJEAN and B. FRIT, J. Phys. Chem. Solids 61 (2000) 1499.Google Scholar
  27. 27.
    C. DUVERGER, M. BOUAZAOUI and S. TURELL, J. Non. Cryst. Solids 220 (1997) 169.Google Scholar
  28. 28.
    T. SEKIYA, N. MOCHIDA and A. SOEJIMA, J. Non. Cryst. Solids 191 (1995) 115.Google Scholar
  29. 29.
    T. SEKIYA, N. MOCHIDA, A. OHTSUKA and M. TONOKAUA, J. Non. Cryst. Solids 191 (1995) 128.Google Scholar
  30. 30.
    Y. DIMITRIEV, J. C. J. BART, V. DIMITROV and M. ARNAUDOV, Z. Anorg. Allg. Chem. 479 (1981) 229.Google Scholar
  31. 31.
    M. E. LINES, J. Non. Cryst. Solids 89 (1987) 143.Google Scholar
  32. 32.
    M. E. LINES, A. E. MILLER, K. NASSAU and K. B. LYONS, J. Non. Cryst. Solids 89 (1987) 163.Google Scholar
  33. 33.
    A. E. MILLER, K. NASSAU, K. B. LYONS and M. E. LINES, J. Non. Cryst. Solids 99 (1988) 289.Google Scholar
  34. 34.
    B. V. R. CHOWDARI and P. PRAMODA KUMARI, J. Phys. Chem. Solids 58(3) (1997) 515.Google Scholar
  35. 35.
    I. V. KITYK and B. SHARAOUI, Phys. Rev B60 (1999) 942.Google Scholar
  36. 36.
    G. E. KHALIL, G. A. ABDEL FATTAH, M. SALAH SHAFIK and Y. BADR, “3rd workshop on photonics and its applicatrions”, IEEE, Cairo,5 Jan.(2002), IEEE Catalog No:01EX509.Google Scholar

Copyright information

© Springer Science + Business Media, Inc. 2005

Authors and Affiliations

  1. 1.Physics Department, Faculty of ScienceAl Azhar UniversityNasr City, CairoEgypt
  2. 2.National Institute of Laser Enhancement Sciences (NILES)Cairo UniversityEgypt

Personalised recommendations