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Inclusion complexes of cyclodextrins with hydrophobic ionic liquids

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Abstract

Two imidazolium-based hexafluorophosphate ionic liquids (ILs), 1-butyl-3-methylimidazolium hexafluorophosphate and 1-dodecyl-3-methylimidazolium hexafluorophosphate, were used to form inclusion complexes (ICs) with α- and β-cyclodextrins (CDs). Formation of the ICs of each CD with each IL was confirmed by the appearance of a characteristic peak in the UV region. Characterisation of the ICs by NMR and FT-IR spectroscopy provided information about the interactions between the host and guest molecules and the structure of the ICs. Temperature-dependent particle size analysis by dynamic light scattering suggested that the size of the host and the guest governs their stability.

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Acknowledgements

Financial support was provided by a sub-project (CPSF-231) from the Higher Education Quality Enhancement Project of the University Grants Commission of Bangladesh financed by World Bank and the Government of Bangladesh. NMR measurements were obtained from the Wazed Miah Science Research Center at Jahangirnagar University.

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Authors and Affiliations

  1. Department of Chemistry, University of Dhaka, Dhaka, 1000, Bangladesh

    Amiya Atahar, M. Muhibur Rahman & Md. Abu Bin Hasan Susan

  2. University Grants Commission of Bangladesh, 29/1 Agargaon, Sher-e-Bangla Nagar, Dhaka, 1217, Bangladesh

    M. Yousuf Ali Mollah

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  1. Amiya Atahar
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  2. M. Yousuf Ali Mollah
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Correspondence to Md. Abu Bin Hasan Susan.

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Atahar, A., Mollah, M.Y.A., Rahman, M.M. et al. Inclusion complexes of cyclodextrins with hydrophobic ionic liquids. J Incl Phenom Macrocycl Chem 92, 301–309 (2018). https://doi.org/10.1007/s10847-018-0848-3

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