Anion binding properties of tris(2-hydroxyphenyl)methanes

Original Article


Tris(2-hydroxyphenyl)methane derivatives (1) displayed excellent selectivity for Cl in comparison with other anions tested (Br, I and NO3 ) by 1H NMR titration experiments. This selectivity is attributed to the fit size and shape of Cl, which favor the formation of a stable host–guest complex with 1 through the multiple intermolecular hydrogen bonds.


Tris(2-hydroxyphenyl)methane Anion receptor Hydroxyl group 

Supplementary material

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Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  1. 1.Department of Chemistry and Chemical Engineering, Graduate School of Science and EngineeringYamagata UniversityYonezawaJapan

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