Physical properties and inclusion interactions of new stilbazolium salts: experimental versus theoretical study

  • Cornelia Stolle
  • Bojidarka Ivanova
  • Michael Spiteller
Original Article


The experimental and theoretical spectroscopic and spectrometric elucidation in solid-state and gas-phase on the interacting ionic species of applied oriented synthetic derivatives on the base of the stilbazolium salts as molecular template was reported. The correlation between the molecular structure, and vibrational properties within THz-regime (10-0.3 THz) was performed. The collective vibrations, and gas-phase stabilized ionic species were comprehensive studied by the Raman spectroscopy and matrix-assisted laser desorption/ionization mass spectrometry, using the embedded organic dyes in host matrixes. The performed solid-state quantum chemical calculations contributed to further understanding of the nature of the guest–host interacting systems as well as to explain the observed optical phenomena within the THz-region.


Matrix-embedded organic dyes Physical properties Mass spectrometry Quantum chemistry 



The authors thank the Deutscher Akademischer Austausch Dienst (DAAD), for a grant within the priority program “Stability Pact South-Eastern Europe” and gratefully thank the Deutsche Forschungsgemeinschaft (DFG) for Grants SPP 255/21-1 and SPP/22-1. The authors also thank the central instrumental laboratories for structural analysis at Technical University Dortmund (TUD, Germany) and the analytical and computational laboratories at the Institute of Environmental Research (INFU) at the TUD.


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Copyright information

© Springer Science+Business Media B.V. 2012

Authors and Affiliations

  • Cornelia Stolle
    • 1
  • Bojidarka Ivanova
    • 1
  • Michael Spiteller
    • 1
  1. 1.Institut für UmweltforschungUniversität DortmundDortmundGermany

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