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Calixarenes grafted with Bu2P(O)CH2O binding groups at the narrow rim: synthesis, structure and extraction of heterometallic Ru/Zn complexes

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Abstract

Calix[n]arenes (n = 4, 6) existing in the cone, 1,3-alternate or 1,3,5-alternate conformations and functionalized by two, four or six Bu2P(O)CH2O groups have been synthesized by the alkylation of hydroxycalix[4,6]arenes with tosylate of dibutylhydroxymethylphosphine oxide. Their molecular and crystal structures as well as binding properties towards of heterometallic Ru/Zn complexes were investigated. Due to the “calixarene effect” the phosphine oxides are effective extractants for the Ru/Zn complexes.

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Acknowledgments

This research was partially supported by the Polish Ministry of Science and Information Society Technologies (grant 4 T09A 068 25), ISTC (grant 3405), STCU (grant 3863), SB RAS-NAS project no. 107, Program of Chemical department of Russian academy of Sciences no. 5.8.2.

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Authors and Affiliations

  1. Siberian Department, Institute of Inorganic Chemistry of the Russian Academy of Science, Novosibirsk, Russia, 630090

    V. G. Torgov, G. A. Kostin, T. V. Us & T. M. Korda

  2. Institute of Organic Chemistry, NAS of Ukraine, Kyiv-94, 66094, Ukraine

    O. V. Klimchuk, S. I. Miroshnichenko & V. I. Kalchenko

  3. Institute of Physical Chemistry, Polish Academy of Sciences, 01-224, Warsaw, Poland

    K. Suwinska

  4. Laboratoire d’Infochimie, University of Strasbourg, 4, Rue B. Pascal, Strasbourg, France

    A. A. Varnek

  5. Faculty of Biology and Environmental Sciences, University of Cardinal Stefan Wyszynski in Warsaw, 01-938, Warsaw, Poland

    K. Suwinska

Authors
  1. V. G. Torgov
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  2. G. A. Kostin
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  3. T. V. Us
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  4. T. M. Korda
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  5. O. V. Klimchuk
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  6. S. I. Miroshnichenko
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  7. K. Suwinska
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  8. A. A. Varnek
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  9. V. I. Kalchenko
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Correspondence to V. I. Kalchenko.

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Torgov, V.G., Kostin, G.A., Us, T.V. et al. Calixarenes grafted with Bu2P(O)CH2O binding groups at the narrow rim: synthesis, structure and extraction of heterometallic Ru/Zn complexes. J Incl Phenom Macrocycl Chem 71, 67–77 (2011). https://doi.org/10.1007/s10847-010-9904-3

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  • DOI: https://doi.org/10.1007/s10847-010-9904-3

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