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Complexation and extraction of non-ferrous metals by calix[n]arene phosphine oxides

  • G. A. Kostin
  • T. V. US
  • T. M. Korda
  • V. G. Torgov
  • N. V. Kuratieva
  • S. I. Miroshnichenko
  • V. I. Kalchenko
Original Article

Abstract

The extraction of non-ferrous metal (M2+) nitrates by the calix[4,6]arenes (L), bearing four or six phosphine oxide donor groups at the upper or at the lower rim, was quantitatively described in the form of [Mn(NO3)2nL] (n = 1, 2) complexes. The extraction constants (Zn2+ > Cu2+ > Co2+ > Ni2+) for the both types of L coincide with Irving-Williams sequence. Calix[4]arenes, phosphorylated at the lower (narrow) rim, provide better stability of ML complexes because of the best spatial fitting of M2+ by the donor groups. For the upper (wide) rim phosphorylated calix[4]arenes M2L and ML2 complexes are more stable. Unusual zwitterionic [Co2(NO3)4L] complex of the lower rim tetraphosphorylated calix[4]arene 1 was determined by X-ray structural analysis.

Keywords

Calixarene Phosphine oxide Extraction Zinc Cobalt Nickel Copper Zwitter-ion structure 

Notes

Acknowledgements

The work was partially supported by ISTC project 3405 and STCU project 3863, joint project SB RAS–NAN Ukraine, project of Russian Academy of Sciences 5.8.2. G. Kostin thanks Arcus-Elsase and Suprachem projects for the fellowship. The authors thank Dr Olga Klimchuk for synthesis of calixarene 5.

References

  1. 1.
    Arnaud-Neu, F., McKervey, M. A., Schwing-Weill, M.: Metal-ion complexation by narrow rim carbonyl derivatives. In: Asfari, Z. et al. (eds.) Calixarene 2001, pp. 385–406. Kluwer Academic Publishers, Dordrecht (2001)Google Scholar
  2. 2.
    Arnaud-Neu, F., Schwing-Weill, M., Dozol, J.F.: Calixarenes for nuclear waste treatment. In: Asfari, Z. et al. (eds.) Calixarene 2001, pp. 642–662. Kluwer Academic Publishers, Dordrecht (2001)Google Scholar
  3. 3.
    Sliwa, W., Kozlowski, C.: Calixarenes and resorcinarenes. Synthesis, properties and application. Wiley-VCH, Wienheim (2009)Google Scholar
  4. 4.
    Alexandratos, S., Natesan, S.: Coordination chemistry of phosphorylated calixarenes and their application to separations science. Ind. Eng. Chem. Res. 39, 3998–4010 (2000)CrossRefGoogle Scholar
  5. 5.
    Delmau, L.H., Simon, N., Schwing-Weill, M.-J., Arnaud-Neu, F., Dozol, J.-F., Eymard, S., Tournois, B., Böhmer, V., Grüttner, C., Musigmann, C., Tunayar, A.: CMPO-substituted’ calix[4]arenes, extractants with selectivity among trivalent lanthanides and between trivalent actinides and lanthanides. Chem. Comm. 1627–1628 (1998)Google Scholar
  6. 6.
    Torgov, V., Kostin, G., Korda, T., Stoyanov, E., Kalchenko, V., Drapailo, A., Kasyan, O., Wipff, G., Varnek, A.: Upper rim thioether derivatives of calix[4, 6]arenes: extraction of fission Pd(II) and Ag(I). Solv. Extract. Ion Exch. 23, 781–801 (2005)CrossRefGoogle Scholar
  7. 7.
    Torgov, V., Kostin, G., Mashukov, V., Korda, T., Drapailo, A., Kasyan, O., Kalchenko, V.: Palladium(II) extraction by sulfur-containing calix[4, 6]arenes from hydrochloric acid solutions. Russ. J. Inorg. Chem. 53, 1809–1815 (2008)CrossRefGoogle Scholar
  8. 8.
    Smirnov, I.V., Karavan, M.D., Efremova, T.I., Babain, V.A., Miroshnichenko, S.I., Cherenok, S.A., Kal’chenko, V.I.: Extraction of Am, Eu, Tc, and Pd from nitric acid solutions with phosphorylated calixarenes. Radiochemistry 49, 482–492 (2007)CrossRefGoogle Scholar
  9. 9.
    Torgov, V.G., Us, T.V., Shul’man, R.S., Korda, T.M., Kostin, G.A., Kal’chenko, V.I.: Extraction of heterometallic complexes of ruthenium and nonprecious metals by phosphorylmethylated calix[4]arenes from nitrate solutions. Russ. J. Inorg. Chem. 53, 1816–1826 (2008)CrossRefGoogle Scholar
  10. 10.
    Torgov, V.G., Shul’man, R.S., Us, T.V., Korda, T.M., Babain, V.A., Smirnov, I.V., Shadrin, A. Yu.: Extraction of fission ruthenium in the form of heterometallic complexes from nitrate–nitrite solutions. Chem. Sustainable Dev. 12:217–224 (2004)Google Scholar
  11. 11.
    Dosol, J.F., Ludwig, R.: Extraction of radioactive metals by calixarenes. In: Moyer, B. (ed.) Ion Exchange and Solvent Extraction: A Series of Advances, vol. 19, pp. 195–319. CRC Press, Boca Raton (2009)Google Scholar
  12. 12.
    Rais, J., Gruner, B.: Metal bis(dicarbollide) extractants and their applications in separation chemistry. In: Marcus, Y., SenGupta, A. (eds.) Ion Exchange and Solvent Extraction: A Series of Advances, vol. 17, pp. 243–335. Marcel Dekker, New York (2004)Google Scholar
  13. 13.
    Klimchuk, O., Atamas, L., Miroshnichenko, S., Kalchenko, V., Smirnov, I., Babain, V., Varnek, A., Wipff, G.: New wide rim phosphomethylated calix[4]arenes in extraction of americium and europium. J. Incl. Phenom. Macrocycl. Chem. 49, 47–56 (2004)CrossRefGoogle Scholar
  14. 14.
    Kalchenko, V., Atamas, L., Klimchuk, O., Rudzevich, V., Rudzevich, Yu., Boyko, V., Drapailo, A., Miroshnichenko, S. Phosphorylated calixarenes in design of receptors for metal cations and organic molecules. Phosphorus Sulfur Silicon Relat Elem 177, 1537–1540 (2002)Google Scholar
  15. 15.
    Bruker AXS Inc: APEX2 (Version 1.08), SAINT (Version 7.03), SADABS (Version 2.11) and SHELXTL (Version 6.12). Bruker Advanced X-ray Solutions, Madison (2004)Google Scholar
  16. 16.
    Greenwood, N.N., Earnshaw, A.: Chemistry of the elements, vol. 2, 2nd edn. Butterworth-Heinemann, London (1997)Google Scholar
  17. 17.
    Bjerrum, J.: Metal-Ammine Formation in Aqueous Solutions. P. Haase, Copenhagen (1940)Google Scholar
  18. 18.
    Kostin, G.A., Borodin, A.O., Torgov, V.G., Kuratieva, N.V., Naumov, D.Yu., Miroshnichenko, S.I., Kalchenko, V.I. Monomeric and polymeric dinuclear complexes of Co(II) or Ni(II) with calix[4]arene-tetraphosphineoxide. J. Incl. Phenom. Macrocycl. Chem. 59, 45–52 (2007)Google Scholar
  19. 19.
    Kostin, G., Borodin, A., Emel`yanov, V., Naumov, D., Virovets, A., Rohmer, M.-M., Varnek, A.: Synthesis and structure of heterometallic compounds of [RuNO(NO2)4OH]2- with triphenyl phosphine oxide complexes of Co(II), Ni (II), and Zn(II). J. Mol. Struct. 837, 63–71 (2007)CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2010

Authors and Affiliations

  • G. A. Kostin
    • 1
  • T. V. US
    • 1
  • T. M. Korda
    • 1
  • V. G. Torgov
    • 1
  • N. V. Kuratieva
    • 1
  • S. I. Miroshnichenko
    • 2
  • V. I. Kalchenko
    • 2
  1. 1.Nikolaev Institute of Inorganic Chemistry SB RASNovosibirskRussia
  2. 2.Institute of Organic Chemistry, National Academy of Sciences of UkraineKyiv-94Ukraine

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