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Investigation of Metal Ion Complexation of π-Coordinate Calixarene Derivatives by Electrospray-Ionization Mass Spectrometry

  • Haruhisa Konishi
  • Kenta Takahashi
  • Makoto Nakamura
  • Hidefumi Sakamoto
  • Keiichi Kimura
Article

Abstract

Complexation of π-coordinate calix[4]arene derivatives toward soft metal ions, silver and thallium (I) ions, has been studied by electrospray-ionization mass spectrometry. Competitive metal–ion complexation of three calix[4]arene derivatives demonstrates a significant effect of olefinic substituents and its location on the silver ion complexation, but there was no effect of them on the thallium ion complexation. The stability constants for the metal ion complexes of the calixarene derivatives in methanol have been successfully determined by a mass-spectrometric method using 18-crown-6 as the reference ligand.

Keywords

π-coordinate calixarene electrospray-ionization mass spectrometry silver and thallium (I) ions stability constant determination 

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References

  1. 1.
    P. Lhoták and S. Shinkai, . Phys. Org. Chem. 10 (1997) 273CrossRefGoogle Scholar
  2. 2.
    H.C. Kang, A.W. Hanson, B. Eaton and V. Boekelheide, . J. Am. Chem. Soc. 107 (1985) 1979CrossRefGoogle Scholar
  3. 3.
    J.C. Ma and D.A. Dougherty, . Chem. Rev. 97 (1997) 1303CrossRefGoogle Scholar
  4. 4.
    E.S. Meadows, S.L. Wall De, L.J. Barbour and G.W. Gokel, . J. Am. Chem. Soc. 123 (2001) 3092CrossRefGoogle Scholar
  5. 5.
    S. Yajima, N. Yoshioka, M. Tanaka and K. Kimura, . Electroanalysis 15 (2003) 1319CrossRefGoogle Scholar
  6. 6.
    N. Yoshioka, S. Yajima and K. Kimura, . Bunseki Kagaku 52 (2003) 689CrossRefGoogle Scholar
  7. 7.
    P. Lhoták, R. Nakamura and S. Shinkai, . Supramol. Chem. 8 (1997) 333CrossRefGoogle Scholar
  8. 8.
    E.C. Kempen and J.S. Brodbelt, . Anal. Chem. 72 (2000) 5411CrossRefGoogle Scholar
  9. 9.
    M. Nakamura, T. Fujioka, H. Sakamoto and K. Kimura, . New J. Chem. 26 (2002) 554CrossRefGoogle Scholar
  10. 10.
    M. Nakamura, K. Takahashi, T. Fujioka, S. Kado, H. Sakamoto and K. Kimura, . J. Am. Soc. Mass Spectr. 14 (2003) 1110CrossRefGoogle Scholar
  11. 11.
    H.J. Bushmann, . Chem. Ber. 118 (1985) 2746CrossRefGoogle Scholar
  12. 12.
    R.M. Izatt, G.A. Clarl, J.D. Lamb, J.E. King and J.J. Christensen, . Thermochim. Acta 97 (1986) 114CrossRefGoogle Scholar

Copyright information

© Springer 2005

Authors and Affiliations

  • Haruhisa Konishi
    • 1
  • Kenta Takahashi
    • 1
  • Makoto Nakamura
    • 1
  • Hidefumi Sakamoto
    • 1
  • Keiichi Kimura
    • 1
  1. 1.Faculty of Systems Engineering, Wakayama UniversityWakayamaJapan

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