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Investigation of Metal Ion Complexation of π-Coordinate Calixarene Derivatives by Electrospray-Ionization Mass Spectrometry

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Abstract

Complexation of π-coordinate calix[4]arene derivatives toward soft metal ions, silver and thallium (I) ions, has been studied by electrospray-ionization mass spectrometry. Competitive metal–ion complexation of three calix[4]arene derivatives demonstrates a significant effect of olefinic substituents and its location on the silver ion complexation, but there was no effect of them on the thallium ion complexation. The stability constants for the metal ion complexes of the calixarene derivatives in methanol have been successfully determined by a mass-spectrometric method using 18-crown-6 as the reference ligand.

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Authors and Affiliations

  1. Faculty of Systems Engineering,, Wakayama University, Sakae-dani 930, Wakayama, 640-8510, Japan

    Haruhisa Konishi, Kenta Takahashi, Makoto Nakamura, Hidefumi Sakamoto & Keiichi Kimura

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  1. Haruhisa Konishi
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  2. Kenta Takahashi
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  3. Makoto Nakamura
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  4. Hidefumi Sakamoto
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  5. Keiichi Kimura
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Correspondence to Keiichi Kimura.

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Konishi, H., Takahashi, K., Nakamura, M. et al. Investigation of Metal Ion Complexation of π-Coordinate Calixarene Derivatives by Electrospray-Ionization Mass Spectrometry. J Incl Phenom Macrocycl Chem 54, 147–152 (2006). https://doi.org/10.1007/s10847-005-5968-x

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  • DOI: https://doi.org/10.1007/s10847-005-5968-x

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