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Chemical Oxidative Polymerization of β-Cyclodextrin/Aniline Inclusion Complex

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Abstract

A β-cyclodextrin (β-CD)/aniline inclusion complex has been synthesized in aqueous solution and characterized by FT-IR and 1H-NMR spectroscopy, chemical analysis and thermogravimetric method. By elemental analysis and 1H-NMR spectroscopy a complex with stoichiometry 1:1.95 and 1:1.8 (β-CD/aniline) respectively, is found. The complexed aniline was polymerized by chemical oxidative polymerization using ammonium peroxydisulfate in water (pH = 7) and 1M HCl aqueous solution. In both cases, after an induction period, insoluble polyanilines (PANIs) are obtained, however, in water at pH = 7, a polypseudorotaxane architecture containing a β-CD molecule to ~14 aniline units has resulted. In acidic conditions, anilinium cation is highly hydrophilic and inclusion complex has a strong tendency to dissociate to free molecules and emeraldine salt of PANI, free of host molecules is synthesized.

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Authors and Affiliations

  1. Electroactive Polymers Department, P. Poni” Institute of Macromolecular Chemistry, 41A Gr. Ghica Voda Alley, 700487, Iasi, Romania

    Mircea Grigoras & Daniel Gheorghe Conduruta

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  1. Mircea Grigoras
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  2. Daniel Gheorghe Conduruta
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Correspondence to Mircea Grigoras.

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Grigoras, M., Conduruta, D.G. Chemical Oxidative Polymerization of β-Cyclodextrin/Aniline Inclusion Complex. J Incl Phenom Macrocycl Chem 54, 101–107 (2006). https://doi.org/10.1007/s10847-005-5039-3

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  • DOI: https://doi.org/10.1007/s10847-005-5039-3

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