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Weak Intermolecular Interactions in the (1:1) Pyridine Solvate of Dibenzotetraaza[14]annulene Copper(II) Complex. The Crystal Structure of [7,16-dibenzoyl-6,8,15,17-tetramethyl-5,14-dihydrodibenzo[b,i][1,4,8,11] [tetraazacyclotetradecinato(2-)- k4N]copper(II)·pyridine

  • Krzysztof Lewiński
  • Julita Eilmes
Article

Abstract

Recrystallization of the title Cu(II) complex from pyridine afforded solid (1:1) pyridine inclusion compound. The crystal structure revealed a pleated-sheet-like arrangement of saddle-shaped molecules of the host, with molecules of pyridine enclathrated within intermolecular cavities. Careful analysis of intermolecular contacts showed that weak aromatic edge-to-face (C–H···Fπ) interactions occur between pyridine and host molecules. The crystal packing appeared to be also stabilized by the host–host C–H···O hydrogen bonds.

Keywords

C–H···O hydrogen bonds C–H···π interactions clathrate crystalline inclusion compound crystal structure dibenzotetraaza[14]annulene Cu(II) complex pyridine solvate 

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Copyright information

© Springer 2005

Authors and Affiliations

  1. 1.Faculty of ChemistryJagiellonian UniversityKrakówPoland

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