Skip to main content
SpringerLink
Log in

Magnetic mesoporous silica: a novel nano-material towards electrochemical sensing

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

This study reports on the synthesis and characterization of a novel magnetic nano-material, Fe3O4 magnetic nanoparticles/mobile crystalline material-41 (Fe3O4 MNP-MCM-41) for sensing some cardiovascular drugs. For the first time, as-synthesized Fe3O4 MNP-MCM-41 is engineered to specifically and effectively capture and enhancement the electrochemical signals of some cardiovascular drugs at different pH due to the synergy among MCM-41 and magnetic nanoparticles. We have illustrated that the as-obtained Fe3O4 MNP-MCM-41 exhibited a much higher electroactivity individual bare carbon past electrode (CPE) for the electrooxidation and detection of selected cardiovascular drugs. Magnetic and specific properties of the Fe3O4 MNP-MCM-41 can be exploited to capture and pre-concentration the selected cardiovascular drugs onto its surface, which are important for detection of multi-drugs. The proposed method was successfully applied to determine selected drugs in human serum, yielding satisfactory results. In general, Fast response time, excellent catalytic activity, lower overvoltage and ease of preparation are the advantages of the proposed nano-sensor.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Scheme 1
Fig. 3

Similar content being viewed by others

References

  1. E. Meng, T. Hoang, Encyclopedia of Applied Electrochemistry 41, 663–668 (2014)

    Article  Google Scholar 

  2. F. S. Ligler, Anal Chem 81, 519 (2009)

    Article  Google Scholar 

  3. J. Soleymani, M. Hasanzadeh, N. Shadjou, M. K. Jafari, J. V. Gharamaleki, M. Yadollahie, A. Jouyban, Mater Sci Eng C 61, 638 (2016)

    Article  Google Scholar 

  4. N. Hashemzadeh, M. Hasanzadeh, N. Shadjou, J. Eivazi-Ziaei, M. Khoubnasabjafari, A. Jouyban, J. Pharm. Anal. doi, 10.1016/j.jpha.2016.03.003

  5. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, J Appl Electrochem 44, 821 (2014)

    Article  Google Scholar 

  6. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, Mater Sci Eng C 38, 197 (2014)

    Article  Google Scholar 

  7. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, RSC Adv 4, 51734 (2014)

    Article  Google Scholar 

  8. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, RSC Adv 4,, 4710 (2014)

    Article  Google Scholar 

  9. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, RSC Adv 4, 6580 (2014)

    Article  Google Scholar 

  10. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, Electrochim Acta 89(660) (2013)

  11. N. Shadjou, M. Hasanzadeh, L. Saghatforoush, R. Mehdizadeh, A. Jouyban, Electrochim Acta 58, 336 (2011)

    Article  Google Scholar 

  12. B. Khalilzadeh, M. Hasanzadeh, S. Sanati, L. Saghatforoush, N. Shadjou, J. E. N. Dolatabadi, P. Sheikhzadeh, Int J Electrochem Sci 6, 4164 (2011)

    Google Scholar 

  13. M. Hasanzadeh, A. Karimzadeh, S. Sadeghi, A. Mokhtarzadeh, N. Shadjou, A. Jouyban. J Mater Sci Mater Electron, doi:10.1007/s10854-016-4590-6

  14. M. Zamani-Kalajahi, M. Hasanzadeh, N. Shadjou, M. Khoubnasabjafari, K. Ansarin, V. Jouyban, A. Jouyban, Surf Eng 31, 194 (2015)

    Article  Google Scholar 

  15. M. Hasanzadeh, N. Shadjou, M. Eskandani, M. de la Guardia, E. Omidinia, Trends Anal Chem 45, 93 (2013)

    Article  Google Scholar 

  16. M. Hasanzadeh, M. H. Pournaghi-Azar, N. Shadjou, A. Jouyban, RSC Adv 4, 4710 (2014)

    Article  Google Scholar 

Download references

Acknowledgments

We gratefully acknowledge the support of this work by Drug Applied Research Center, Tabriz University of Medical Sciences.

Author information

Authors and Affiliations

  1. Drug Applied Research Center and Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, 51664, Iran

    Mohammad Hasanzadeh

  2. Pharmaceutical Analysis Research Center and Faculty of Pharmacy, Tabriz University of Medical Sciences, Tabriz, 51664, Iran

    Mohammad Hasanzadeh & Abolghasem Jouyban

  3. Department of Nanochemistry, Nano Technology Center, Urmia University, Urmia, 57154, Iran

    Nasrin Shadjou

  4. Department of Chemistry, Faculty of Chemistry, Urmia University, Urmia, 57154, Iran

    Nasrin Shadjou

  5. Electroanalytical Chemistry Laboratory, Faculty of Chemistry, University of Tabriz, Tabriz, Iran

    Mohammad Hossein Pournaghi-Azar

Authors
  1. Mohammad Hasanzadeh
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. Nasrin Shadjou
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. Mohammad Hossein Pournaghi-Azar
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. Abolghasem Jouyban
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to Mohammad Hasanzadeh.

Rights and permissions

Reprints and permissions

About this article

Check for updates. Verify currency and authenticity via CrossMark

Cite this article

Hasanzadeh, M., Shadjou, N., Pournaghi-Azar, M.H. et al. Magnetic mesoporous silica: a novel nano-material towards electrochemical sensing. J Electroceram 37, 85–91 (2016). https://doi.org/10.1007/s10832-016-0033-2

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-016-0033-2

Keywords

Search

Navigation