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Structural and electrochemical properties of LiNi0.7Co0.15Mn0.15O2 thin film prepared by high frequency hybrid direct current and radio frequency magnetron sputtering

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Abstract

A LiNi0.7Co0.15Mn0.15O2 thin film cathode has been successfully prepared by hybrid direct current - radio frequency magnetron sputtering onto glass substrate from the LiNi0.7Co0.15Mn0.15O2 target and post-annealed by the rapid thermal annealing process. Its structure and morphology were characterized by X-ray diffraction, and scanning electron microscopy while its chemical compositions were confirmed with the inductively coupled plasma atomic absorption spectrophotometer, Raman spectroscopy, Auger electron spectroscopy, and glow discharge spectrometer. Its electrochemical properties were measured by galvanostatic charge - discharge test and cyclic voltammetry. First discharge capacity of 73 μAh∙cm−2∙μm−1 was obtained from a half cell with the LiNi0.7Co0.15Mn0.15O2 thin film cathode and lithium metal anode in the potential range of 4.3 ~ 2.5 V at 30 μA and its coulombic efficiency was more than 99 %.

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References

  1. J.B. Bates, N.J. Dudney, A. Ueda, C.D. Evans, Solid State Ionics 135, 33 (2000)

    Article  CAS  Google Scholar 

  2. W.G. Choi, S.G. Yoon, J. Power Sources 125, 236 (2004)

    Article  CAS  Google Scholar 

  3. H.K. Kim, T.Y. Seong, Y.S. Yoon, Thin Solid Films 447, 619 (2004)

    Article  Google Scholar 

  4. M. Tarascon, E. Wang, F.K. Shokoohi, W.R. Mckinnon, S. Colson, J. Electrochem. Soc. 138, 2859 (1991)

    Article  CAS  Google Scholar 

  5. H. A. Kiehne, Battery Technology Handbook, 2nd edn. (CRC Pres, South Korea, 2003)

  6. M. Wakihara, Mater. Sci. Eng. R. 33, 109 (2001)

    Article  Google Scholar 

  7. C. Julien, E. Haro-Poniatowski, M.A. Camacho-Lopez, L. Escobar-Alarcon, J. Jimenez-Jarquin, Mater. Sci. Eng. B 72, 36 (2000)

    Article  Google Scholar 

  8. P. Liu, J.G. Zang, T.A. Turner, C.E. Tracy, D.K. Benson, J. Electrochem. Soc. 146, 2001 (1999)

    Article  CAS  Google Scholar 

  9. D. Shu, K.Y. Chung, W.I. Cho, K.B. Kim, J. Power Sources 114, 253 (2003)

    Article  CAS  Google Scholar 

  10. F.K. Shokoohi, J.M. Tarascon, B.J. Wilkens, Appl. Phys. Lett. 59, 1260 (1991)

    Article  CAS  Google Scholar 

  11. M.R. Tomy, K.M.A. Kumer, P.B. Anand, S. Jayalekshmi, J. Phys. Chem. Soc. 73, 559 (2012)

    Article  CAS  Google Scholar 

  12. S. Komaba, N. Kumagai, M. Baba, F. Miura, N. Fujita, H. Groult, D. Devilliers, B. Kaplan, J. Appl. Electrochem. 30, 1179 (2000)

    Article  CAS  Google Scholar 

  13. K.H. Hwang, S.H. Lee, S.K. Joo, J. Electrochem. Soc. 141, 3296 (1994)

    Article  CAS  Google Scholar 

  14. B.J. Hwang, C.Y. Wang, M.Y. Cheng, R. Santhanam, J. Phys. Chem. C 113, 11373 (2009)

    Article  CAS  Google Scholar 

  15. J.B. Bates, N.J. Dudney, D.C. Lubben, G.R. Gruzalski, B.S. Kwak, X. Yu, R.A. Zuhr, J. Power Sources 54, 58 (1995)

    Article  CAS  Google Scholar 

  16. P. Ho Young, N. Sang Cheol, L. Young Chang, C. Kyu Gil, L. Ki Chang, P. Gi Back, K. Jae Bum, K. Heesook Park, C. Sung Baek, Electrochim. Acta 52, 2062 (2007)

    Article  Google Scholar 

  17. Y.I. Jang, B.J. Neudecker, N.J. Dudney, Electrochem. Solid-State Lett. 4, A74–A77 (2001)

    Article  CAS  Google Scholar 

  18. W. Huang, R. Frech, Solid State Ionic 395, 86 (1996)

    Google Scholar 

  19. L. Mendoza, R. Baddour-Hadjean, M. Cassir, J.P. Pereira-Ramos, Appl. Surf. Sci. 225, 356 (2004)

    Article  CAS  Google Scholar 

  20. S. Tintignac, R. Baddour-Hadjean, J.P. Pereira-Ramos, R. Salot, Electrochim. Acta 60, 121 (2012)

    Article  CAS  Google Scholar 

  21. C.S. Nimisha, G.M. Rao, J. Appl. Phys. 109, 114910 (2011)

    Article  Google Scholar 

  22. R. Baddour-Hadjean, J.P. Pereira-Ramos, Chem. Rev. 110, 1278 (2010)

    Article  CAS  Google Scholar 

  23. K.M. Shaju, G.V. Subba Rao, B.V.R. Chowdari, Electrochim. Acta 48, 145 (2002)

    Article  CAS  Google Scholar 

  24. A. Castro-Couceiro, S. Castro-Garcia, M.A. Senaris-Rodriguez, F. Soulette, C. Julien, Solid State Ionics 156, 15 (2003)

    Article  Google Scholar 

  25. I. Saadoune, C. Delmas, Solid State Ionics 370, 53 (2003)

    Google Scholar 

  26. G. Wang, M.J. Lindsay, M. Ionescu, D.H. Bradhurst, S.X. Dou, H.K. Liu, J. Power Sources 97–98, 298 (2001)

    Article  Google Scholar 

  27. M. Takahashi, M. Hayashi, T. Shodai, J. Power Sources 189, 191 (2009)

    Article  CAS  Google Scholar 

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Acknowledgments

This work was supported and grant funded by GS Caltex Corporation and by the International collaboration research program supported by MKW (20118510010030) and by MKW (2011201010016C)

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Authors and Affiliations

  1. Center for Energy Convergence, Korea Institute of Science and Technology, 14gil-5, Hwarang-ro, Seongbuk-gu, Seoul, 136-791, Korea

    Youngmin Chung, Si-hyoung Oh, Dong Young Yoon & Won Il Cho

  2. Energy Materials Lab., R&D Center, GS Caltex Corp., Deajeon, Korea

    Ho-young Park, Sang-wan Jin & Dong-yoon Jang

  3. Department of Chemical and Biological Engineering, Hanbat National University, 125, Yuseong-gu, Daejeon, 305-719, Korea

    Jang Myoun Ko

  4. Spintronic Material Lab., Department of Materials Science and Engineering, Korea University, 145, Anam-ro, Seongbuk-gu, Seoul, 136-701, Korea

    Seong-Rae Lee

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  1. Youngmin Chung
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  3. Si-hyoung Oh
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  4. Dong Young Yoon
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  9. Seong-Rae Lee
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Correspondence to Jang Myoun Ko or Won Il Cho.

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Chung, Y., Park, Hy., Oh, Sh. et al. Structural and electrochemical properties of LiNi0.7Co0.15Mn0.15O2 thin film prepared by high frequency hybrid direct current and radio frequency magnetron sputtering. J Electroceram 31, 316–323 (2013). https://doi.org/10.1007/s10832-013-9845-5

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  • DOI: https://doi.org/10.1007/s10832-013-9845-5

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