Skip to main content
SpringerLink
Log in

Phase formations during mechanochemical synthesis of PbTiO3

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

Lead titanate nanopowders were fabricated by mechanochemical synthesis from lead oxide and titanium dioxide. The milling process has been carefully investigated by X-ray diffraction and X-ray excited photoelectron spectroscopy. The first traces of perovskite phase were detected after 5 h synthesis. It was found that intermediated phases (Ti10O18 and Pb3O4) have been formed at the early stage of synthesis. The 50 h milling results in single perovskite phase with average crystallite size of 20 nm.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Fig. 1
Fig. 2
Fig. 3

Similar content being viewed by others

References

  1. J. M. Xue, D. M. Wan, S. E. Lee, J. Wang, J. Am. Ceram. Soc. 82, 1689 (1999)

    Article  Google Scholar 

  2. H. A. M. van Hak, W. A. Groen, S. Maassen, W. C. Keur, J. Eur. Ceram. Soc. 21, 1689 (2001)

    Article  Google Scholar 

  3. L. B. Kong, J. Ma, W. Zhu, O. K. Tan, Mater. Lett. 52, 378 (2002)

    Article  CAS  Google Scholar 

  4. V. Pavlović, M. V. Nikolić, V. B. Pavlović, N. Labus, L. Živković, B. D. Stojanović, Ferroelectrics 319, 75 (2005)

    Article  CAS  Google Scholar 

  5. J. M. Xue, Z. H. Zhou, J. Wang, in Encyclopedia of Nanoscience and Nanotechnology, vol. 6, ed. by H.S. Nalwa (American Scientific Publishers, Stevenson Ranch, CA, 2004), pp. 417–433

  6. J. Wang, D. Wan, J. Xue, US Patent 6627104 (2003-09-30)

  7. K. Uchino, Ferroelectric Devices (Marcel Dekker, New York, 2000)

    Google Scholar 

  8. I. Szafraniak, M. Połomska, B. Hilczer, E. Talik, L. Kępiński, Ferroelectrics 336, 279 (2006)

    Article  CAS  Google Scholar 

  9. ICDD Diffraction Date, International Center for Powder Diffraction (1997)

  10. S. Chattopadhyay, P. Ayyub, V. R. Palkar, M. Multani, Phys. Rev. B 52, 13177 (1995)

    Article  CAS  Google Scholar 

  11. B. Jiang, L. A. Bursill, Phys. Rev. B 60, 9978 (1999)

    Article  CAS  Google Scholar 

  12. B. Jiang, J. L Peng, L. A. Bursill, W. L. Zhong, J. Appl. Phys. 87, 3462 (2000)

    Article  CAS  Google Scholar 

  13. E. K. Akdogan, C. J. Rawn, W. D. Porter, E. A. Payzant, A. Safari, J. Appl. Phys. 97, 084305 (2005)

    Article  CAS  Google Scholar 

  14. R. J. Nelmes, W. F. Kuhs, Solid State Commun. 54, 721 (1985)

    Article  CAS  Google Scholar 

  15. A. I. Akimov, G. K. Savchuk, V. A. Rubtsov, A. K. Letko, Crystallogr. Rep. 48, 239 (2003)

    Article  CAS  Google Scholar 

  16. J. F. Moulder, W. F. Stickle, P. E. Sobol, K. D. Bomben, in Handbook of X-ray Photoelectron Spectroscopy (Physical Electronics Inc, Minnesota, 1995)

  17. R. J. Cole, N. J. Brooks, P. Weightman, Phys. Rev. Lett. 78, 3777 (1997)

    Article  CAS  Google Scholar 

  18. J. Chen, J. Lian, L. M. Wang, W. Pan, Phys. Rev. Lett. 88, 105901 (2002)

    Article  CAS  Google Scholar 

Download references

Acknowledgement

This work was partially founded by Polish Ministry of Science (PBZ-MIN-012/KBN/2004) and European Commission (POLECER G5RT-CT-2001-05024).

Author information

Authors and Affiliations

  1. Institute of Materials Science and Engineering, Poznań University of Technology, M. Skłodowska-Curie Sq. 5, 60-965, Poznań, Poland

    I. Szafraniak-Wiza

  2. Institute of Molecular Physics, Polish Academy of Sciences, M. Smoluchowskiego 17, 60-179, Poznań, Poland

    I. Szafraniak-Wiza & B. Hilczer

  3. Institute of Low Temperature and Structure Research, Polish Academy of Sciences, Okólna 2, 50-422, Wrocław, Poland

    A. Pietraszko

  4. Institute of Physics, Silesian University, Uniwersytecka 4, 40-007, Katowice, Poland

    E. Talik

Authors
  1. I. Szafraniak-Wiza
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. B. Hilczer
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. A. Pietraszko
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. E. Talik
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to I. Szafraniak-Wiza.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Szafraniak-Wiza, I., Hilczer, B., Pietraszko, A. et al. Phase formations during mechanochemical synthesis of PbTiO3 . J Electroceram 20, 21–25 (2008). https://doi.org/10.1007/s10832-007-9339-4

Download citation

  • Received:

  • Accepted:

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-007-9339-4

Keywords

Search

Navigation