Skip to main content
SpringerLink
Log in

Characterization and dielectric properties of Ba5LnNiTa9O30 (Ln = La, Nd and Sm) ceramics

  • Published:
Journal of Electroceramics Aims and scope Submit manuscript

Abstract

Three novel Ba5LnNiTa9O30 (Ln = La, Nd and Sm) ceramics were prepared and characterized in the BaO-Ln2O3-NiO-Ta2O5 system. All three compounds adopted the filled tetragonal tungsten bronze (TB) structure at room temperature. The present ceramics exhibited relaxor behavior, and the Curie temperature (at 10kHz) were −130, −80 and −45°C for Ba5LaNiTa9O30, Ba5NdNiTa9O30, and Ba5SmNiTa9O30 respectively. At room temperature, Ba5LnNiTa9O30 ceramics have a high dielectric constants in the range 102∼118, a low dielectric loss in range 0.0019∼0.0036, and the temperature coefficients of the dielectric constant (τɛ) in the range −320∼−460 ppm°C−1 (at 1 MHz).

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. R.R. Neurgaonkar and W.K. Cory, J. Opt. Soc. Am. B, 3, 274 (1986).

    CAS  Google Scholar 

  2. R.R. Neurgaonkar, J.G. Nelson, J.R. Oliver, L.E. Cross, and W.K. Cory, Mater. Res. Bull., 25, 959 (1990).

    Article  CAS  Google Scholar 

  3. R.R. Neurgaonkar, J.G. Nelson, and J.R. Oliver, Mater. Res. Bull., 27, 677 (1992).

    Article  CAS  Google Scholar 

  4. N. Wakiya, J.K. Wang, A. Saiki, K. Shinozaki, and N. Mizutani, J. Eur. Ceram. Soc., 19, 1071 (1999).

    Article  CAS  Google Scholar 

  5. L. Fang, H. Zhang, B.L. Wu, and R.Z. Yuan, J. Progress in Crystal Growth and Characterization of Materials, 40, 161 (2000).

    CAS  Google Scholar 

  6. A. Panigrahi and N.K. Singh, J. Mat. Sci. Lett., 18, (1999) 1579.

    Article  CAS  Google Scholar 

  7. P. Koshy, L.P. Kumari, and M.T. Sebastian, J. Mat. Sci: Mater. Electron., 9, 43 (1998).

    CAS  Google Scholar 

  8. R.P. Rao, S.K. Ghosh, and P. Koshy, J. Mat. Sci: Mater. Electron., 12, 729 (2001).

    CAS  Google Scholar 

  9. X.M. Chen, Y.H. Sun, and X.H. Zheng, J. Eur. Ceram. Soc., 23, 1571 (2003).

    CAS  Google Scholar 

  10. X.H. Zheng and X.M. Chen, Solid State Communications, 125, 449 (2003).

    Article  CAS  Google Scholar 

  11. L. Fang, H. Zhang, J.B. Yan, and W.M. Yang, Acta Phys.-Chim. Sin, 19, 82 (2003).

    CAS  Google Scholar 

  12. H. Zhang, L. Fang, T.H. Huang, H.X. Liu, R.Z. Yuan, and R. Dronskowski, J. Mat. Sci., 40, 529 (2005).

    CAS  Google Scholar 

  13. L. Fang, H. Zhang, R.Z. Yuan, and R. Dronskowski, J. Mat. Sci: Mater. Electron., 15, 699 (2004).

    CAS  Google Scholar 

  14. Liang Fang, H. Zhang, J.F. Yang, F.H. Meng, and R.Z. Yuan, Mater. Lett., 58, 1777 (2004).

    CAS  Google Scholar 

  15. L. Fang, H. Zhang, J.F. Yang, X.K. Hong, and F.C. Meng, J. Mat. Sci: Mater. Electron, 15, 355 (2004).

    CAS  Google Scholar 

  16. L. Fang, L. Chen, H. Zhang, C.L. Diao, and R.Z. Yuan, Mater. Lett., 58, 2654 (2004).

    CAS  Google Scholar 

  17. H. Zhang, L. Fang, T.H. Huang, R.Z. Yua, and R. Dronskowski, J. Mat. Sci., 40, 515 (2005).

    CAS  Google Scholar 

  18. H. Zhang, L. Fang, J.F. Yang, R.Z. Yuan, and H.X. Liu, J. Mat. Sci: Mater. Electron., 15, 327 (2004).

    Google Scholar 

  19. L. Fang, H. Zhang, J.F. Yang, R.Z. Yuan, and H.X. Liu, Mater. Res. Bull., 39, 677 (2004).

    CAS  Google Scholar 

  20. L. Fang, H. Zhang, T. H. Huang, H. X. Liu, R.Z. Yuan, J. Mater. Sci., 39, 1903 (2004).

    CAS  Google Scholar 

  21. H. Zhang, L. Fang, T.H. Huang, C.L. Diao, R.Z. Yuan, and R. Dronskowski, J. Mat. Sci: Mater. Electron., 15, 695 (2004).

    CAS  Google Scholar 

  22. R.D. Shannon, Acta. Crystall., A32, 751 (1976).

    CAS  Google Scholar 

  23. J.A. Dean, Lange’s Handbook of Chemistry, 15th ed. (McGraw-Hill, New York, 1999).

    Google Scholar 

  24. S.M. Pilgrim, A.E. Sutherland, and S.R. Winzer, J. Am. Ceram. Soc., 73, 3122 (1990).

    Article  CAS  Google Scholar 

  25. M.R. Ranga Raju, and R.N.P. Choudhary, J. Physics and Chemistry of Solids, 64, 847 (2003).

    CAS  Google Scholar 

Download references

Author information

Authors and Affiliations

  1. State Key Lab. of Advanced Technology for Materials Synthesis and Processing, Wuhan University of Technology, Wuhan, 430070, People’s Republic of China

    L. Fang, H. Zhang, T. H. Huang, F. C. Meng & J. F. Yang

Authors
  1. L. Fang
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. H. Zhang
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. T. H. Huang
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. F. C. Meng
    View author publications

    You can also search for this author in PubMed Google Scholar

  5. J. F. Yang
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to L. Fang.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Fang, L., Zhang, H., Huang, T.H. et al. Characterization and dielectric properties of Ba5LnNiTa9O30 (Ln = La, Nd and Sm) ceramics. J Electroceram 16, 135–139 (2006). https://doi.org/10.1007/s10832-006-4299-7

Download citation

  • Received:

  • Revised:

  • Accepted:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10832-006-4299-7

Keywords

Search

Navigation