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Signals of Isotopomers in 13C NMR Spectra of Polyisoprene Rubbers

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Journal of Applied Spectroscopy Aims and scope

Analysis of 13C-satellites was carried out in the 13C NMR spectra of isoprene rubbers with a natural content of 13C carbon isotope. 13C-satellites are the signals caused by the one-bond spin–spin coupling of 13C nuclei. The spin–spin coupling 1J(13C–13C) constants, as well as the magnitude of the effect of the isotopic substitution 1Δδ13C(13/12C), were measured under magnetic shielding of 13C nuclei. The results indicate that the configurational and local conformational structure of natural and synthetic isoprene rubbers is identical.

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References

  1. J. Tanaka and H. Sato, Polymer, 17, No. 2, 113–116 (1976).

    Article  Google Scholar 

  2. W. Gronski, N. Murayama, H. J. Cantow, and T. Miyamoto, Polymer, 17, No. 4, 358–360 (1976).

    Article  Google Scholar 

  3. M. Morese-Seguela, M. St. Jacques, J. M. Renaud, and J. Prudhomme, Macromolecules, 10, No. 2, 431–432 (1977).

    Article  ADS  Google Scholar 

  4. H. Sato, A. Ono, and Y. Tanaka, Polymer, 18, No. 6, 580–586 (1977).

    Article  Google Scholar 

  5. A. S. Khatchaturov, E. R. Dolinskaya, L. K. Prozenko, E. L. Abramenko, and V. A. Kormer, Polymer, 18, No. 9, 871–877 (1977).

    Article  Google Scholar 

  6. D. Xie and Q. Sun, Chin. J. Polym. Sci., 5, No. 2, 114–119 (1987).

    Google Scholar 

  7. D. Xie and Q. Sun, Acta Polym. Sin., No. 1, 1–6 (1988).

  8. Z. W. Qiu, X. Chen, B. Sun, Z. Zhou, and F. Wang, J. Macromol. Sci., A25, No. 2, 127–141 (1988).

    Article  Google Scholar 

  9. N. Makhiyanov, I. G. Akhmetov, and A. M. Vagizov, Polym. Sci., А54, No. 12, 942–949 (2012).

    Google Scholar 

  10. V. A. Rozentsvet, N. A. Korovina, O. A. Stotskaya, M. G. Kuznetsova, F. Peruch, and S. V. Kostjuk, J. Polym. Sci., A: Polym. Chem., 54, 2430–2442 (2016).

    Article  ADS  Google Scholar 

  11. N. Makhiyanov, Polym. Sci., А59, No. 2, 269–279 (2017).

    Google Scholar 

  12. G. J. Ray and C. M. Szabo, eMagRes, 2, No. 2, 193–204 (2013).

    Google Scholar 

  13. K. Hatada, T. Kitayama, J. Terawaki, Y. Tanaka, and H. Sato, Polym. Bull., 2, No. 11, 791–797 (1980).

    Article  Google Scholar 

  14. G. Audi, O. Bersillon, J. Blachot, and A. H. Wapstra, Nucl. Phys., A729, No. 1, 3–128 (2003).

    Article  ADS  Google Scholar 

  15. L. B. Krivdin and E. W. Della, Progr. NMR Spectr., 23, No. 4, 301–610 (1991).

    Article  Google Scholar 

  16. G. Becher, W. Liittke, and G. Schrumpf, Angew. Chem., 85, No. 8, 357–358 (1973).

    Article  Google Scholar 

  17. Th. Fäcke and S. Berger, J. Am. Chem. Soc., 117, No. 37, 9547–9550 (1995).

    Article  Google Scholar 

  18. Ch.-J. Park, G.-Ch. Han, and S.-G. Lee, Bull. Korean Chem. Soc., 21, No. 11, 1159–1161 (2000).

    Google Scholar 

  19. A. V. Chertkov, A. K. Shestakova, and V. A. Chertkov, Chem. Heterocycl. Comp., 48, No. 3, 412–421 (2012).

    Article  Google Scholar 

  20. W. Gombler, J. Am. Chem. Soc., 104, No. 24, 6616–6620 (1982).

    Article  Google Scholar 

  21. C. J. Jameson and H. J. Osten, Ann. Rep. NMR Spectr., 17, No. 1, 1–78 (1986).

    Google Scholar 

  22. P. E. Hansen, Progr. NMR Spectr., 20, No. 3, 207–255 (1988).

    Article  Google Scholar 

  23. L. B. Krivdin and G. A. Kalabin, Progr. NMR Spectrosc., 21, Nos. 4–5, 293–448 (1989).

    Article  Google Scholar 

  24. K. Kamienska-Trela, Ann. Rep. NMR Spectr., 30, 131–230 (1995).

    Article  Google Scholar 

  25. M. Barfield, I. Burfitt, and D. Doddrell, J. Am. Chem. Soc., 97, No. 10, 2631–2634 (1975).

    Article  Google Scholar 

  26. J. E. Mark, J. Am. Chem. Soc., 88, No. 19, 4354–4359 (1966).

    Article  Google Scholar 

  27. Y. Abe and P. Flory, Macromolecules, 4, No. 2, 230–237 (1971).

    Article  ADS  Google Scholar 

  28. N. Makhiyanov, M. M. Minnegaliev, and R. M. Aminova, Polym. Sci., A58, No. 2, 121–129 (2016).

    Google Scholar 

  29. Y. Tanaka and L. Tarachiwin, Rubb. Chem. Technol., 82, No. 3, 283–314 (2009).

    Article  Google Scholar 

  30. T. Kitaura, M. Kobayashi, L. Tarachiwin, H. Kum-ourm, A. Matsuura, K. Fushihara, and K. Ute, Macromol. Chem. Phys., 219, No. 3, 1700331 (2018).

    Article  Google Scholar 

  31. N. Makhiyanov and A. S. Khatchaturov, Polym. Sci., A52, No. 2, 209–219 (2010).

    Google Scholar 

  32. L. J. Fetters, D. J. Lohsey, and R. H. Colby, in: J. E. Mark (Ed.), Physical Properties of Polymers Handbook, Springer, New York (2007), pp. 447–454.

    Chapter  Google Scholar 

  33. A. Bax, R. Freeman, and S. P. Kempsell, J. Am. Chem. Soc., 102, No. 14, 4849–4851 (1980).

    Article  Google Scholar 

  34. T. Jézéquel, V. Joubert, P. Giraudeau, G. S. Remaud, and S. Akoka, Magn. Reson. Chem., 55, No. 2, 77–90 (2017).

    Article  Google Scholar 

Download references

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  1. Public Joint Stock Company “Nizhnekamskneftekhim”, 423574, Nizhnekamsk, Tatarstan, Russia

    N. Makhiyanov

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  1. N. Makhiyanov
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Correspondence to N. Makhiyanov.

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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 85, No. 6, pp. 912–918, November–December, 2018.

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Makhiyanov, N. Signals of Isotopomers in 13C NMR Spectra of Polyisoprene Rubbers. J Appl Spectrosc 85, 1037–1043 (2019). https://doi.org/10.1007/s10812-019-00756-x

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  • DOI: https://doi.org/10.1007/s10812-019-00756-x

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