Journal of Applied Spectroscopy

, Volume 85, Issue 1, pp 1–8 | Cite as

Influence of Intermolecular Interactions and Axial Ligands on the Absorption Spectra of Metallophthalocyanines in Solid-State Matrices

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The influences of the structure of the anionic axial ligands in Group-IIIA and -IVA metal–phthalocyanine complexes and intermolecular interactions on the absorption spectra of the macroheterocycles in solutions, an organic polymer, and nanoporous silicate gel matrices were studied. It was shown that anionic Cl – ligands of the central metal ion were effectively substituted for hydroxyls (OH –) during the synthesis and purification of the metallophthalocyanines. Studies of solid-state nanoporous samples obtained by the sol-gel method showed that activator hydroxoaluminumphthalocyanine molecules were incorporated as monomers into the organo-inorganic silicate material. The optically homogeneous luminescent xerogel could be used in optical devices for the wavelength range adjacent to the near-IR region.

Keywords

metallophthalocyanines sol-gel synthesis nanoporous silicate matrices electronic absorption spectrum IR spectrum ligand exchange monomeric and aggregated forms 

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References

  1. 1.
    A. N. Cammidge and R. J. Bushby, in: Handbook of Liquid Crystals, D. Demus, J. Goodby, G. W. Gray, H.-W. Spiess, and V. Vill (Eds.), Vol. 2B, Wiley VCH, Weinheim (1998), pp. 693–743.Google Scholar
  2. 2.
    M. Hanack, T. Schneider, M. Barthel, J. S. Shirk, S. R. Flom, and R. G. S. Pong, Coord. Chem. Rev., 219221, 235–258 (2001).Google Scholar
  3. 3.
    S. R. Flom, in: The Porphyrin Handbook, K. M. Kadish, K. M. Smith, and R. Guilard (Eds.), Vol. 19, Academic Press, San Diego (2003), pp. 179–190.Google Scholar
  4. 4.
    G. de la Torre, P. Vazquez, F. Agullo-Lopez, and T. Torres, Chem. Rev., 104, 3723–3750 (2004).CrossRefGoogle Scholar
  5. 5.
    M. Bouvet, Anal. Bioanal. Chem., 384, 366–373 (2006).CrossRefGoogle Scholar
  6. 6.
    A. Sorokin, Chem. Rev., 113, 8152–8191 (2013).CrossRefGoogle Scholar
  7. 7.
    C. G. Claessens, W. J. Blau, M. Cook, M. Hanack, R. J. M. Nolte, T. Torres, and D. Wohrle, Monatsh. Chem., 132, 3–11 (2001).CrossRefGoogle Scholar
  8. 8.
    R. Bonnett, Chemical Aspects of Photodynamic Therapy, Gordon and Breach Science Publ., Amsterdam (2000), pp. 199–224.Google Scholar
  9. 9.
    H. Ali and J. E. van Lier, in: Handbook of Porphyrin Science, K. M. Kadish, K. M. Smith, and R. Guilard (Eds.), Vol. 4, World Scientific Publ. Co., Singapore (2010), pp. 1–119.Google Scholar
  10. 10.
    S. M. Arabei, T. A. Pavich, and K. N. Solovyov. J. Porphyrins Phthalocyanines, 17, 636–648 (2013).CrossRefGoogle Scholar
  11. 11.
    M. K. Lowery, A. J. Starshak, J. N. Esposito, P. C. Krueger, and M. E. Kenney, Inorg. Chem., 4, 128 (1965).CrossRefGoogle Scholar
  12. 12.
    A. S. Akopov, B. D. Berezin, V. N. Klyuev, and A. A. Solov’ev, Zh. Neorg. Khim., 17, 981–984 (1972).Google Scholar
  13. 13.
    C. W. Dirk, T. Inabe, K. F. Schoch, Jr., and T. J. Marks, J. Am. Chem. Soc., 105, 1539–1550 (1983).CrossRefGoogle Scholar
  14. 14.
    R. D. Joyner and M. E. Kenney, J. Am. Chem. Soc., 82, 5790–5791 (1960).CrossRefGoogle Scholar
  15. 15.
    W. Freyer and Le quoc Minh, Monatsh. Chem., 117, 475–489 (1986).Google Scholar
  16. 16.
    J. W. Buchler, in: Porphyrins and Metalloporphyrins, K. M. Smith (Ed.), Elsevier Scientific Publishing Company, Amsterdam (1975), pp. 157–231.Google Scholar
  17. 17.
    E. A. Luk′yanets (Ed.), Electronic Spectra of Phthalocyanines and Related Compounds. Catalog. Moscow NPO NIOPIK [in Russian], NIITEKhIM, Cherkassy (1989).Google Scholar
  18. 18.
    T. Fukuda and N. Kobayashi, in: Handbook of Porphyrin Science, K. M. Kadish, K. M. Smith, and R. Guilard (Eds.), Vol. 9, World Scientifi c Publ. Co., Singapore (2010), pp. 1–644.Google Scholar
  19. 19.
    E. Ciliberto, K. A. Doris, W. J. Pietro, G. M. Reisner, D. E. Ellis, I. Fragala, F. H. Herbstein, M. A. Ratner, and T. J. Marks, J. Am. Chem. Soc., 106, 7748–7761 (1984).CrossRefGoogle Scholar
  20. 20.
    I. Seotsanyana-Mokhosi, N. Kuznetsova, and T. Nyokong, J. Photochem. Photobiol. A, 140, 215–222 (2001).Google Scholar
  21. 21.
    Z. Ou, J. Shen, and K. M. Kadish, Inorg. Chem., 45, 9569–9579 (2006).CrossRefGoogle Scholar
  22. 22.
    T. N. Sokolova, T. N. Lomova, S. V. Zaitseva, S. A. Zdanovich, and V. E. Maizlish, Russ. J. Inorg. Chem., 53, 220–228 (2008).CrossRefGoogle Scholar
  23. 23.
    G. P. Shaposhnikov, V. E. Maizlish, and V. P. Kulinich, Russ. J. Gen. Chem., 75, 1480–1488 (2005).CrossRefGoogle Scholar
  24. 24.
    V. Chauke, A. Ogunsipe, M. Durmuş, and T. Nyokong, Polyhedron, 26, 2663–2671 (2007).CrossRefGoogle Scholar
  25. 25.
    M. Durmuş and T. Nyokong, Polyhedron, 26, 3323–3335 (2007).CrossRefGoogle Scholar
  26. 26.
    Y. Chen, Y. Araki, M. Fujitsuka, M. Hanack, O. Ito, S. M. O’Flaherty, and W. J. Blau, Solid State Commun., 131, 773–778 (2004).ADSCrossRefGoogle Scholar
  27. 27.
    A. W. Snow, in: The Porphyrin Handbook, K. M. Kadish, K. M. Smith, and R. Guilard (Eds.), 17, Academic Press, San Diego (2003), pp. 129–176.Google Scholar
  28. 28.
    I. Ya. Markova, Yu. A. Popov, and Yu. Kh. Shaulov, Zh. Fiz. Khim., 44, 2636–2638 (1970).Google Scholar
  29. 29.
    A. S. Akopov, B. D. Berezin, and V. N. Klyuev, Izv. Vyssh. Uchebn. Zaved., Khim. Khim. Tekhnol., 15, 1190–1192 (1972).Google Scholar
  30. 30.
    A. R. Kane, J. F. Sullivan, D. H. Kenny, and M. E. Kenney, Inorg. Chem., 9, 1445–1448 (1970).CrossRefGoogle Scholar
  31. 31.
    B. D. Berezin and A. S. Akopov, Zh. Obshch. Khim., 44, 1089–1093 (1974).Google Scholar
  32. 32.
    J. H. Brannon and D. Magde, J. Am. Chem. Soc., 102, 62–65 (1980).CrossRefGoogle Scholar
  33. 33.
    P. C. Martin, M. Gouterman, B. V. Pepich, G. E. Renzoni, and D. C. Schindele, Inorg. Chem., 30, 3305–3309 (1991).CrossRefGoogle Scholar
  34. 34.
    H. Xiang, J. Cheng, X. Ma, X. Zhou, and J. J. Chruma, Chem. Soc. Rev., 42, 6128–6185 (2013).CrossRefGoogle Scholar

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© Springer Science+Business Media, LLC, part of Springer Nature 2018

Authors and Affiliations

  1. 1.B. I. Stepanov Institute of Physics of the National Academy of Sciences of BelarusMinskBelarus
  2. 2.Belarusian State Agrarian and Technical UniversityMinskBelarus

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