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Synthesis and Characterization of a Novel Ligand and Spectroscopic Study of the Formation of its Complexes with Different Cations and Their Sensory Characteristics

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Journal of Applied Spectroscopy Aims and scope

A new ligand (L), N,N′-bis(2-hydroxybenzyl)-1,2-diaminoethane, was synthesized and characterized. The sensing behavior of L toward various metal ions was investigated by spectrofluorometric and UV-Vis spectrophotometric methods. The sensor displayed selective and sensitive recognition toward Fe3+ and Fe2+ in acetonitrile. The fluorescence of L was quenched mainly by Fe3+, and a considerable enhancement of fluorescence was observed in the presence of Zn2+. Using multivariate hard modeling and stoichiometry, the concentration, spectral profiles, and formation constants of the studied complexes were calculated.

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Authors and Affiliations

  1. Razi University, Department of Analytical Chemistry, Faculty of Chemistry, Kermanshah, Iran

    M. Shariati-Rad & M. Karimi

  2. Department of Chemical Engineering, Hamedan University of Technology, Hamedan, 65155, Iran

    M. Rezaeivala

Authors
  1. M. Shariati-Rad
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  2. M. Karimi
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  3. M. Rezaeivala
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Corresponding author

Correspondence to M. Shariati-Rad.

Additional information

Abstract of article is published in Zhurnal Prikladnoi Spektroskopii, Vol. 84, No. 6, p. 1014, November–December, 2017.

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Shariati-Rad, M., Karimi, M. & Rezaeivala, M. Synthesis and Characterization of a Novel Ligand and Spectroscopic Study of the Formation of its Complexes with Different Cations and Their Sensory Characteristics. J Appl Spectrosc 84, 1089–1097 (2018). https://doi.org/10.1007/s10812-018-0593-9

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  • DOI: https://doi.org/10.1007/s10812-018-0593-9

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