Journal of Applied Spectroscopy

, Volume 83, Issue 3, pp 362–366 | Cite as

Theoretical and Experimental Investigation of Terahertz Absorption Spectra for Water Clusters (H2O) n (n = 4, 5, 6) in the Atmosphere

  • Y. D. Wu
  • T. Zhou
  • Z. W. Yao
  • J. C. Cao

The atmosphere transmission spectrum is measured from 0.2 to 1.6 THz with a continuous wave spectrometer. Three ring-formed water clusters of (H 2 O) n (n = 4, 5, 6) are proposed and their THz absorption spectra are calculated with the density functional theory. The calculated absorption lines of (H 2 O)6 agree well with the measured spectrum, which indicates that the resonant absorptions in the atmosphere are caused by the ring-formed water clusters in the studied frequency range. The discrepancy between the calculation and experiment results on the absorptions around 1.2 THz should be ascribed to the deformation of the cluster.


density functional theory water cluster continuous wave terahertz spectroscopy 


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  1. 1.
    D. M. Slocum, E. J. Slingerland, R. H. Giles, and T. M. Goyette, J. Quant. Spectrosc. Radiat. Transf., 127, 49–63 (2013).ADSCrossRefGoogle Scholar
  2. 2.
    Y. H. Yang, A. Shutler, and D. Grischkowsky, Opt. Express, 19, 8830–8838 (2011).ADSCrossRefGoogle Scholar
  3. 3.
    H. Hoshina, T. Seta, T. Iwamoto, I. Hosako, C. Otani, and Y. Kasai, J. Quant. Spectrosc. Radiat. Transf., 109, 2303–2314 (2008).ADSCrossRefGoogle Scholar
  4. 4.
    V. H. Payne, J. S. Delamere, K. E. Cady-Pereira, R. R. Gamache, J. L. Moncet, E. J. Mlawer, and S. A. Clough, IEEE Trans. Geosci. Remote Sensing, 46, 3601–3617 (2008).ADSCrossRefGoogle Scholar
  5. 5.
    V. B. Podobedov, D. F. Plusquellic, K. E. Siegrist, G. T. Fraser, Q. Ma, and R. H. Tipping, J. Quant. Spectrosc. Radiat. Transf., 109, 458–467 (2008).ADSCrossRefGoogle Scholar
  6. 6.
    V. B. Podobedov, D. F. Plusquellic, and G. T. Fraser, J. Quant. Spectrosc. Radiat. Transf., 91, 287–295 (2005).ADSCrossRefGoogle Scholar
  7. 7.
    V. B. Podobedov, D. F. Plusquellic, K. M. Siegrist, G. T. Fraser, Q. Ma, and R. H. Tipping, J. Mol. Spectrosc., 251, 203–209 (2008).ADSCrossRefGoogle Scholar
  8. 8.
    J. C. Jiang, Y. S. Wang, H. C. Chang, S. H. Lin, Y. T. Lee, G. Niedner-Schatteburg, and H. C. Chang, J. Am. Chem. Soc., 122, 1398–1410 (2000).CrossRefGoogle Scholar
  9. 9.
    J. O. Jung and R. B. Gerber, J. Chem. Phys., 105, 10332 (1996).ADSCrossRefGoogle Scholar
  10. 10.
    L. Huang, S. G. Lambrakos, A. Shabaev, N. Bernstein, and L. Massa, Passive and Active Millimeter-Wave Imaging XVII, 9078, 8 (2014).Google Scholar
  11. 11.
    J. O. Richardson, D. J. Wales, S. C. Althorpe, R. P. McLaughlin, M. R. Viant, O. Shih, and R. J. Saykally, J. Phys. Chem. A, 117, 6960–6966 (2013).CrossRefGoogle Scholar
  12. 12.
    K. Kim, K. D. Jordan, and T. S. Zwier, J. Am. Chem. Soc., 116, 11568–11569 (1994).CrossRefGoogle Scholar
  13. 13.
    J. M. Pedulla, F. Vila, and K. D. Jordan, J. Chem. Phys., 105, 11091 (1996).ADSCrossRefGoogle Scholar
  14. 14.
    A. Roggenbuck, H. Schmitz, A. Deninger, I. C. Mayorga, J. Hemberger, R. Güsten, and M. Grüninger, New J. Phys., 12, 043017 (2010).ADSCrossRefGoogle Scholar
  15. 15.
    15 . D. Stanze, A. Deninger, A. Roggenbuck, S. Schindler, M. Schlak, and B. Sartorius, J. Infrared, Millimeter, and Terahertz Waves, 32, 225–232 (2010).Google Scholar
  16. 16.
    A. Roggenbuck, M. Langenbach, K. Thirunavukkuarasu, H. Schmitz, A. Deninger, I. Cámara Mayorga, R. Güsten, J. Hemberger, and M. Grüninger, J. Opt. Soc. Am. B, 30, 1397 (2013).ADSCrossRefGoogle Scholar
  17. 17.
    R . A. Cheville and D. Grischkowsky, Opt. Lett., 20, 1646–1648 (1995).ADSCrossRefGoogle Scholar
  18. 18.
    K . He, J. Sun, and X. Tang, IEEE Trans. Pattern Anal. Machine Intellig., 35, 1397–1409 (2013).CrossRefGoogle Scholar
  19. 19.
    M . Hakala, K. Nygard, S. Manninen, S. Huotari, T. Buslaps, A. Nilsson, L. G. M. Pettersson, and K. Ha-malainen, J. Chem. Phys., 125, 7 (2006).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Shanghai Institute of Microsystem and Information TechnologyChinese Academy of SciencesShanghaiChina
  2. 2.Huashan HospitalFudan UniversityShanghaiChina

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