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Journal of Applied Spectroscopy

, Volume 82, Issue 6, pp 920–924 | Cite as

Reaction Mechanism of Lead(II) Oxide With A PbCl2–CsCl Melt According to Raman Spectroscopic Data

  • I. D. Zakir′yanova
  • P. A. Arkhipov
  • D. O. Zakir′yanov
Article

The reaction mechanism of lead(II) oxide and PbCl2–CsCl melt was studied in situ using Raman spectroscopy. The types, structures, and compositions of ionic species present in the melt were determined. It was found that dissolution of PbO followed the reaction [PbCl 3  + Cs+](l) + 2 PbO(s) → [Pb3O2Cl+ + Cs+ + 2 Cl] (l) and was accompanied by the appearance of [Pb3O2Cl]+ oxychloride ions.

Keywords

Raman spectroscopy lead oxide lead oxychloride melt 

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  • I. D. Zakir′yanova
    • 1
    • 2
  • P. A. Arkhipov
    • 1
  • D. O. Zakir′yanov
    • 2
  1. 1.Institute of High-Temperature Electrochemistry, Ural BranchRussian Academy of SciencesEkaterinburgRussia
  2. 2.B. N. Yeltsin Ural Federal UniversityEkaterinburgRussia

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