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Journal of Applied Spectroscopy

, Volume 82, Issue 4, pp 521–531 | Cite as

Calculation and Comparative Analysis of the IR Spectra of Homobrassinolide and (22S,23S)-Homobrassinolide

  • V. M. Andrianov
  • M. V. Korolevich
Article

Normal vibrational frequencies and absolute IR band intensities of the biologically active steroid phytohormones homobrassinolide and (22S,23S)-homobrassinolide were calculated in the framework of an original approach that combined classical analysis of normal modes using molecular mechanics with quantum-chemical estimation of the absolute intensities. IR absorption bands were interpreted based on a comparison of the experimental and theoretical absorption spectra. The impact of structural differences in the side chains of these molecules on the formation of their IR spectra in the region 1500–950 cm −1 was estimated.

Keywords

infrared spectra normal coordinate analysis absolute intensities characteristic frequencies brassinosteroids brassinolides 

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© Springer Science+Business Media New York 2015

Authors and Affiliations

  1. 1.B. I. Stepanov Institute of Physics, National Academy of Sciences of BelarusMinskBelarus
  2. 2.Belarusian State Agrarian Technical UniversityMinskBelarus

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