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Phase Equilibria and Ionic Solvation in the Lithium Tetrafluoroborate–Dimethylsulfoxide System

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Journal of Applied Spectroscopy Aims and scope

The phase diagram and electrical conductivity isotherms for the lithium tetrafluoroborate (LiBF4)–dimethylsulfoxide (DMSO) system and Raman spectra of DMSO and the LiBF4–DMSO solution were studied. Spectroscopic signatures of a H-bond between DMSO and BF4 − ions were found. The bonds of Li+ ions to the solvent were stronger than the bonds in DMSO dimers because formation of the solvate destroyed dimeric DMSO molecules. The τω values for DMSO molecules in the Li+-ion solvate shell of the LiBF4–DMSO system were similar to those for associated solvent molecules.

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Authors and Affiliations

  1. Analytical Center for Collective Use, Dagestan Scientifi c Center, Russian Academy of Sciences, 45 M. Gadzhiev Str., Makhachkala, 367025, Russia

    M. M. Gafurov, K. Sh. Rabadanov & M. B. Ataev

  2. Inter-Agency Department of Electrochemical Energy Systems, National Academy of Sciences of Ukraine, Kiev, Ukrain

    S. A. Kirillov, M. I. Gorobets & D. O. Tretyakov

  3. Institute of Sorption and Endoecological Problems, National Academy of Sciences of Ukraine, Kiev, Ukrain

    S. A. Kirillov

  4. Dagestan State University, Makhachkala, Russia

    K. M. Aydemirov

Authors
  1. M. M. Gafurov
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  2. S. A. Kirillov
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  3. M. I. Gorobets
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  4. K. Sh. Rabadanov
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  5. M. B. Ataev
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  6. D. O. Tretyakov
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  7. K. M. Aydemirov
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Correspondence to M. M. Gafurov.

Additional information

Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 81, No. 6, pp. 824–830, November–December, 2014.

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Gafurov, M.M., Kirillov, S.A., Gorobets, M.I. et al. Phase Equilibria and Ionic Solvation in the Lithium Tetrafluoroborate–Dimethylsulfoxide System. J Appl Spectrosc 81, 912–918 (2015). https://doi.org/10.1007/s10812-015-0028-9

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  • DOI: https://doi.org/10.1007/s10812-015-0028-9

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