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Journal of Applied Spectroscopy

, Volume 81, Issue 5, pp 750–753 | Cite as

Selective Stimulation of Conformational Conversions in Free Molecules

  • G. I. Ismailzade
  • I. Z. Movsumov
  • M. R. Menzeleev
  • S. B. Kazymova
Article
  • 25 Downloads

Application of double-resonance (RF-MW, IR-MW, MW-MW) methods to enhance studies of unstable isomeric structures was discussed. The use of infrared pump radiation to excite conformational energy levels in order to stimulate selectively conformational conversions and to correct spectral line intensities of separate conformations was substantiated.

Keywords

rotational spectrum conformational conversion double quantum resonance Hamiltonian 

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Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • G. I. Ismailzade
    • 1
  • I. Z. Movsumov
    • 1
  • M. R. Menzeleev
    • 1
  • S. B. Kazymova
    • 1
  1. 1.Institute of Physics, National Academy of Sciences of AzerbaijanBakuAzerbaijan

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