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Journal of Applied Spectroscopy

, Volume 81, Issue 2, pp 188–192 | Cite as

Optical Properties of Polyimide Films Implanted with Ni+ Ions

  • Yu. A. Bumai
  • N. I. Dolgikh
  • A. A. Kharchenko
  • V. F. Valeev
  • V. I. Nuzhdin
  • R. I. Khaibullin
  • F. A. Nagim
  • M. G. Lukashevich
  • V. B. Odzhaev
Article
  • 58 Downloads

Transmission and refl ection spectra of polyimide fi lms 40-μm thick implanted with 40-keV Ni+ ions at fl uences 2.5·1016–1.5·1017 cm–2 and ion-beam current density 4, 8, and 12 μA/cm2 were studied in the range 200–1100 nm. It was shown that the optical transmission coeffi cient decreased smoothly after implantation as a result of light absorption and scattering in the modifi ed polymer layer containing nano-sized inclusions of C and Ni. The appearance of a broad refl ection band in the range 700–1100 nm in spectra from the implanted polymer and the reverse side of the polymer was due to a high Ni content in the implanted layer. The refractive index of the modifi ed implanted polymer layer that varied in the range 1.25–2.32 at 620 nm depending on the fl uence was determined by modeling the passage of light through the bilayer modifi ed layer/polymer matrix taking into account multiple refl ections at the interfaces.

Keywords

ion implantation polyimide nickel refl ection transmission refractive index 

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References

  1. 1.
    U. Kreibig and M. Vollmer, Optical Properties of Metal Clusters, Springer, Berlin (1995), pp. 12–134.Google Scholar
  2. 2.
    S. A. Maier, Plasmonics: Fundamentals and Applications, Springer Verlag, Berlin (2007), pp. 166–196.Google Scholar
  3. 3.
    S. V. Gaponenko, Introduction to Nanophotonics, Cambridge University Press, Cambridge, New York (2010).Google Scholar
  4. 4.
    A. L. Stepanov and R. I. Khaibullin, Rev. Adv. Mater. Sci., 7, No. 2, 108–125 (2004).Google Scholar
  5. 5.
    Yu. A. Bumai, V. S. Volobuev, V. F. Valeev, N. I. Dolgikh, M. G. Lukashevich, R. I. Khaibullin, V. I. Nuzhdin, and V. B. Odzhaev, Zh. Prikl. Spektrosk., 79, No. 5, 781–787 (2012).Google Scholar
  6. 6.
    Yu. A. Bumai, V. F. Valeev, N. I. Dolgikh, M. G. Lukashevich, F. A. Nazhim, V. I. Nuzhdin, and V. B. Odzhaev, Mater., Tekhnol., Instrum., 15, No. 4, 54–58 (2010).Google Scholar
  7. 7.
    A. Mackova, J. Bocan, R. I. Khaibullin, V. F. Valeev, P. Slepicka, P. Sajdl, and V. Svorcik, Nucl. Instrum. Methods Phys. Res., Sect. B, 267, 1549–1552 (2009).CrossRefADSGoogle Scholar
  8. 8.
    P. Malinsky, A. Mackova, V. Hnatowicz, R. I. Khaibullin, V. F. Valeev, P. Slepicka, V. Svorcik, M. Slouf, and V. Perina, Nucl. Instrum. Methods Phys. Res., Sect. B, 272, 396–399 (2012).CrossRefADSGoogle Scholar
  9. 9.
    A. V. Mitrofanov, P. Yu. Apel′, I. V. Blonskaya, and O. L. Orelovich, Zh. Tekh. Fiz., 76, No. 9, 121–127 (2006).Google Scholar
  10. 10.
    I. P. Kozlov, V. B. Odzhaev, I. A. Karpovich, V. N. Popok, and D. V. Sviridov, Zh. Prikl. Spektrosk., 65, No. 3, 377–381 (1998).Google Scholar
  11. 11.
    E. T. Arakawa, M. W. Williams, J. C. Ashely, and L. R. Painter, J. Appl. Phys., 52, No. 5, 3579–3582 (1981).CrossRefADSGoogle Scholar
  12. 12.
    V. V. Lebedeva, Techniques of Optical Spectroscopy [in Russian], Izd. MGU, Moscow (1977).Google Scholar
  13. 13.
    Yu. A. Bumai, N. I. Dolgikh, A. A. Kharchenko, M. G. Lukashevich, and V. B. Odzhaev, Vestn. Beloruss. Gos. Univ., Ser. 1, No. 2, 41–44 (2011).Google Scholar
  14. 14.
    Yu. A. Bumai, D. I. Brinkevich, N. I. Dolgikh, I. A. Karpovich, A. A. Kharchenko, M. G. Lukashevich, and V. B. Odzhaev, Vestsi Nats. Akad. Navuk Belarusi, Ser. Fiz.-Mat. Navuk, No. 1, 92–96 (2013).Google Scholar
  15. 15.
    A. V. El′tsov (Ed.), Light-sensitive Polymers [in Russian], Khimiya, Leningrad (1985).Google Scholar
  16. 16.
    M. S. Dresselhaus and G. Dresselhaus, Adv. Phys., 51, No. 1, 1–186 (2002).CrossRefADSGoogle Scholar
  17. 17.
    E. A. Konshina, Amorphous Hydrogenated Carbon and Its Application in Optical Devices [in Russian], SPbGU ITMO, St. Petersburg (2010), pp. 25–40.Google Scholar

Copyright information

© Springer Science+Business Media New York 2014

Authors and Affiliations

  • Yu. A. Bumai
    • 1
  • N. I. Dolgikh
    • 2
  • A. A. Kharchenko
    • 2
  • V. F. Valeev
    • 3
  • V. I. Nuzhdin
    • 3
  • R. I. Khaibullin
    • 3
    • 4
  • F. A. Nagim
    • 5
  • M. G. Lukashevich
    • 2
  • V. B. Odzhaev
    • 2
  1. 1.Belarusian National Technical UniversityMinskRussia
  2. 2.Belarusian State UniversityMinskBelarus
  3. 3.Kazan Physical-Technical Institute, Kazan Scientifi c CenterRussian Academy of SciencesKazanRussia
  4. 4.Kazan (Volga Region) Federal UniversityKazanRussia
  5. 5.Al-Qadisiya UniversityAl-Qadisiya-DiwaniyaIraq

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