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Journal of Applied Spectroscopy

, Volume 79, Issue 2, pp 189–196 | Cite as

Surface enhanced infrared spectral investigation of 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone on silver nanoparticles

  • M. Umadevi
  • P. Vanelle
  • T. Terme
Article
  • 73 Downloads

The size effect of silver nanoparticles on photophysical properties of 2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone (BCMAT) has been investigated using an IR technique. Silver colloids of different sizes have been prepared by two different methods. Mechanisms for adsorption and complex formation have been elucidated from surface-enhanced infrared absorption spectra. The observation shows that BCMAT is adsorbed on silver nanoparticles through a C = O group and that its orientation is stand-on. Surface enhancement factors have been calculated. As the particles decrease in size their total surface area grows, which leads to the gain in the enhancement factor.

Keywords

2,3-bis(chloromethyl)anthracene-1,4,9,10-tetraone silver nanoparticles surface-enhanced infrared absorption spectroscopy 

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Copyright information

© Springer Science+Business Media, Inc. 2012

Authors and Affiliations

  1. 1.Department of PhysicsMother Teresa Women’s UniversityTamil NaduIndia
  2. 2.Laboratory of Radical Pharmaco-Chemistry, UMR CNRS 6264University of the Méditerranée, Faculty of PharmacyMarseilleFrance

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