Journal of Applied Spectroscopy

, Volume 77, Issue 1, pp 55–59 | Cite as

Luminescence spectra fine structure for uranyl sulfate and oxalate crystals


Quasi-line low-temperature (T = 77 and 4.2 K) luminescence spectra of uranyl sulfates and oxalates have been recorded and analyzed. It has been shown that the spectral structure is determined by the manifestation of the internal and external vibrations of both the uranyl ion and molecular groups (SO4)2– and (C2O4)2–bonded to the uranyl ion. The spectral line half-width is of the order of ≈5–7 cm–1; the line shape, close to Lorentzian. The fluorescence spectra may be complicated by structural defects in the crystals.


crystal sulfate oxalate uranyl luminescence spectrum fine structure. 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    L. V. Volod’ko, A. I. Komyak, and D. S. Umreiko, Uranyl Compounds, Vol. 1, Spectra and Structure [in Russian], Izd. Bel. Gos. Univ., Minsk (1981).Google Scholar
  2. 2.
    I. I. Chernyaev, ed., Complex Compounds of Uranium [in Russian], Nauka, Moscow (1964).Google Scholar
  3. 3.
    A. P. Zazhogin, A. I. Komyak, and D. S. Umreiko, Vestn. Bel. Gos. Univ., Ser. Fiz., No. 1, 17–23 (2007).Google Scholar
  4. 4.
    M. V. Barashkov, A. I. Komyak, and S. N. Shashkov, Zh. Prikl. Spektrosk., 67, No. 2, 162–167 (2000).Google Scholar
  5. 5.
    V. N. Boikov, A. N. Krasovskii, and D. S. Umreiko, Zh. Prikl. Spektrosk., 37, No. 5, 790–795 (1982).Google Scholar
  6. 6.
    A. N. Krasovskii, V. N. Boikov, and D. S. Umreiko, Zh. Prikl. Spektrosk., 40, No. 3, 441–446 (1984).Google Scholar
  7. 7.
    K. Murata and M. Morita, J. Lumin., 29, No. 4, 381–386 (1984).CrossRefGoogle Scholar
  8. 8.
    R. G. Denning, C. N. Ironside, T. R. Snellgrove, and P. J. Stone, J. Chem. Soc., Dalton Trans., 9, No. 9, 1691–1697 (1982).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2010

Authors and Affiliations

  • A. I. Komyak
    • 1
  • A. P. Zazhogin
    • 1
  • D. S. Umreiko
    • 1
  1. 1.Belarusian State UniversityMinskBelarus

Personalised recommendations