The composites xTiO2-(1−x)SiO2 (x = 0.1, 0.5, 0.9) were obtained by coprecipitation from solutions of alkoxides: tetraethoxysilane (TEOS) and titanium tetraisopropoxide (TIPT). Intermolecular interaction of the components of the composite is apparent in the IR absorption spectra in the 928–952 cm−1 region, and is connected with bending vibrations of the Si-O-Ti bond.
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K. M. S. Khalil, A. A. Elsamahy, and M. S. Elanany, J. Colloid and Interface Sci., 359, 359–365 (2002).
M. M. Mokhtar, T. M. Salama, and T. Yamaguchi, Coll. Surf. A: Physicochem. Eng. Aspects, 207, 25–32 (2002).
Z. Li, B. Hou, Y. Xu, D. Wu, and Y. Sun, J. Colloid and Interface Sci., 288, 149–154 (2005).
Z.-L. Hua, J.-L. Shi, L.-X. Zhang, M.-L. Ruan, and Ji-Na Yan, Adv. Mater., 14, No. 11, 830–833 (2002).
H. Yamashita, S. Nishio, I. Katayama, N. Nishiyama, and H. Fujii, Catalysis Today, 111, 254–258 (2006).
A. Matsuda, Y. Higashi, K. Tanada, and M. Tatsumisago, J. Mater. Sci., 41, 8101–8108 (2006).
A. N. Murashkevich and A. S. Lavitskaya, Vestsi NAN Belarusi, Ser. Khim. Navuk, No. 2 5–11 (2007).
A. Ennaoui, B. R. Sankapal, V. Skryshevsky, and M. Ch. Lux-Steiner, Solar Energy Mater. & Solar Cells, 90, 1533–1541 (2006).
D. Panayotov and J. T. Yates, Chem. Phys. Lett., 381, 154–162 (2003).
Z. Yasong and J. Guowei, Chin. J. Chem. Eng., 10, No. 3, 349–353 (2002).
Z. Li, B. Hou, Y. Xu, D. Wu, Y. Sun, W. Hu, and F. Deng, J. Solid State Chem., 178, 1395–1405 (2005).
A. V. Kiselev and V. I. Lygin, Infrared Spectra of Surface Compounds [in Russian], Nauka, Moscow (1972).
N. A. Chumaevskii, Vibrational Spectra of Heteroorganic Compounds of Group IV-B and V-B Elements [in Russian], Nauka, Moscow (1971), pp. 59–61.
F. S. R. Lenza and W. L. Vasconcelos, Mater. Res., 5, No. 4, 125–131 (2002).
E. N. Yurchenko, G. N. Kustova, and S. S. Batsanov, Vibrational Spectra of Inorganic Compounds [in Russian], Nauka, Novosibirsk (1981), pp. 111–112.
C. Xie, Z. Xu, Q. Yang, B. Xue, Y. Du, and J. Zhang, Mater. Sci. & Eng. B, 112, 34–41 (2004).
C. F. Song, M. K. Lu, S. F. Wang, D. Xu, D. R. Yuan, and G. J. Zhou, Neorg. Mater., 39, No. 12, 1529–1531 (2003).
J. M. Fraile, J. I. Garcia, J. A. Mayoral, and E. Vispe, J. Catal., 233, 90–99 (2005).
P. Cheng, M. Zheng, Y. Jin, Q. Huang, and M. Gu, Mater. Lett., 57, 2989–2994 (2003).
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Translated from Zhurnal Prikladnoi Spektroskopii, Vol. 75, No. 5, pp. 724–728, September–October, 2008.
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Murashkevich, A.N., Lavitskaya, A.S., Barannikova, T.I. et al. Infrared absorption spectra and structure of TiO2-SiO2 composites. J Appl Spectrosc 75, 730–734 (2008). https://doi.org/10.1007/s10812-008-9097-3
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DOI: https://doi.org/10.1007/s10812-008-9097-3