Journal of Applied Spectroscopy

, Volume 75, Issue 4, pp 500–505 | Cite as

Interaction of β-cyclodextrin with mercury(II) nitrate

  • A. N. Shvets
  • D. Yu. Lyashenko
  • L. A. Belyakova


The interaction of β-cyclodextrin with mercury(II) nitrate has been studied using UV, IR, and 1H NMR spectroscopy, elemental analysis, and quantitative chemical analysis. The optimum conditions for complex formation were established. The stability constant of the 1:1 inclusion complex of β-cyclodextrin and nitrate was calculated. The formation of supermolecules of composition C42H70O35·3Hg(NO3)2 in solution and on a silica surface chemically modified with β-cyclodextrin was shown.

Key words

β-cyclodextrin mercury(II) nitrate inclusion complex supermolecule chemical modification silica surface 


Unable to display preview. Download preview PDF.

Unable to display preview. Download preview PDF.


  1. 1.
    R. Hedges, Chem. Rev., 98, 2035–2044 (1998).CrossRefGoogle Scholar
  2. 2.
    B. Pose-Vilarnovo, I. Perdomo-Lopez, M. Echezarreta-Lopez, et al., J. Pharm. Sci., 13, 325–331 (2001).CrossRefGoogle Scholar
  3. 3.
    R. Stancanelli, A. Mazzaglia, S. Tommasini, et al., J. Pharm. Biomed. Anal., 44, 980–984 (2007).CrossRefGoogle Scholar
  4. 4.
    S. K. Panda, W. Schrader, and J. T. Andersson, J. Chromatogr. A, 1122, 88–96 (2006).CrossRefGoogle Scholar
  5. 5.
    S. Rozou, A. Voulgari, and E. Antoniadou-Vyza, J. Pharm. Sci., 21, 661–669 (2004).CrossRefGoogle Scholar
  6. 6.
    A. R. Khan, P. Forgo, K. J. Stine, et al., Chem. Rev., 98, 1977–1996 (1998).CrossRefGoogle Scholar
  7. 7.
    S. Shiraishi, M. Komiyama, and H. Hiray, Bull. Chem. Soc. Jpn., 59, 507–510 (1986).CrossRefGoogle Scholar
  8. 8.
    M. H. Prousoontorn and S. Pantatan, J. Inclusion Phenom. Macrocyclic Chem., 57, 39–46 (2007).CrossRefGoogle Scholar
  9. 9.
    I. Abe, T. Fukuhara, N. Kawasaki, et al., J. Colloid Interface Sci., 229, 615–619 (2000).CrossRefGoogle Scholar
  10. 10.
    L. A. Belyakova, D. Yu. Lyashenko, A. M. Varvarin, et al., Ukr. Khim. Zh., 71, 86–92 (2005).Google Scholar
  11. 11.
    L. A. Belyakova, A. M. Varvarin, D. Yu. Lyashenko, and O. M. Shvets, in: Proc. Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Application, Univ. Marii Curie-Sklodowskiej, Sandomierz (2005).Google Scholar
  12. 12.
    O. M. Shvets and L. A. Belyakova, in: Proc. Theoretical and Experimental Studies of Interfacial Phenomena and Their Technological Application, Lviv Natl. Univ., Lviv (2006).Google Scholar
  13. 13.
    G. Shvartsenbakh and G. Flashka, Complexometric Titration [in Russian], Khimiya, Moscow (1970).Google Scholar
  14. 14.
    C. N. R. Rao, Electronic Spectra in Chemistry [Russian translation], Mir, Moscow (1961).Google Scholar
  15. 15.
    X. Wen, F. Tan, Z. Jing, and Z. Liu, J. Pharm. Biomed. Anal., 34, 517–523 (2004).CrossRefGoogle Scholar
  16. 16.
    W. West and A. B. F. Duncan, eds., Chemical Applications of Spectroscopy, Interscience Publishers, New York (1956).Google Scholar
  17. 17.
    H. J. Schneider, F. Hacket, V. Rudiger, et al., Chem. Rev., 98, 1755–1785 (1998).CrossRefGoogle Scholar
  18. 18.
    Y. Matsui, M. Ono, and S. Tokunaga, Bull. Chem. Soc. Jpn., 70, 535–541 (1997).CrossRefGoogle Scholar
  19. 19.
    G. S. Borodkin, I. G. Borodkina, A. I. Uraev, et al., Ross. Khim. Zh., 48, 117–124 (2004).Google Scholar
  20. 20.
    M. Chen, G. Diao, and E. Zhang, Chemosphere, 63, 522–529 (2005).CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • A. N. Shvets
    • 1
  • D. Yu. Lyashenko
    • 1
  • L. A. Belyakova
    • 1
  1. 1.A. A. Chuiko Institute of Surface ChemistryNational Academy of Sciences of UkraineKievUkraine

Personalised recommendations