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Journal of Applied Spectroscopy

, Volume 75, Issue 4, pp 500–505 | Cite as

Interaction of β-cyclodextrin with mercury(II) nitrate

  • A. N. Shvets
  • D. Yu. Lyashenko
  • L. A. Belyakova
Article

Abstract

The interaction of β-cyclodextrin with mercury(II) nitrate has been studied using UV, IR, and 1H NMR spectroscopy, elemental analysis, and quantitative chemical analysis. The optimum conditions for complex formation were established. The stability constant of the 1:1 inclusion complex of β-cyclodextrin and nitrate was calculated. The formation of supermolecules of composition C42H70O35·3Hg(NO3)2 in solution and on a silica surface chemically modified with β-cyclodextrin was shown.

Key words

β-cyclodextrin mercury(II) nitrate inclusion complex supermolecule chemical modification silica surface 

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Copyright information

© Springer Science+Business Media, Inc. 2008

Authors and Affiliations

  • A. N. Shvets
    • 1
  • D. Yu. Lyashenko
    • 1
  • L. A. Belyakova
    • 1
  1. 1.A. A. Chuiko Institute of Surface ChemistryNational Academy of Sciences of UkraineKievUkraine

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