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Journal of Applied Spectroscopy

, Volume 74, Issue 3, pp 374–378 | Cite as

Comparative analysis of high-resolution spectra of naphthalene and its methyl-substituted derivatives cooled in a supersonic jet

  • G. G. D’yachenko
  • V. A. Petukhov
  • M. A. Semenov
Article
  • 35 Downloads

Abstract

We have carried out a comparative analysis of fine-structure fluorescence excitation and fluorescence spectra of naphthalene, 2,6-and 2,7-dimethylnaphthalene, and 2-methylnaphthalene molecules cooled in a supersonic jet. We have shown that both the frequencies and the intensities of most of the lines in the spectra of these molecules are correlated. Such a correlation facilitates interpretation of the spectra in the case when it is difficult to calculate the transition intensities and when lines corresponding to vibrations of different symmetry have close frequencies. For the considered molecules, a preliminary assignment of the lines in the fine-structure spectra is refined.

Key words

fluorescence excitation spectrum fluorescence naphthalene methyl-substituted naphthalene supersonic jet correlation 

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References

  1. 1.
    J. A. Warren, J. M. Hayes, and G. J. Small, J. Chem. Phys., 80, 1786–1790 (1984).CrossRefADSGoogle Scholar
  2. 2.
    N. A. Borisevich, G. G. D’yachenko, V. A. Petukhov, and M. A. Semenov, Opt. i Spektr., 101, 736–743 (2006).CrossRefGoogle Scholar
  3. 3.
    N. A. Borisevich, L. B. Vodovatov, G. G. D’yachenko, V. A. Petukhov, and M. A. Semenov, Spectrosc. Lett., 35, 879–899 (1997).CrossRefGoogle Scholar
  4. 4.
    N. A. Borisevich, L. B. Vodovatov, G. G. D’yachenko, V. A. Petukhov, and M. A. Semenov, Opt. i Spektr., 78, 241–248 (1995).Google Scholar
  5. 5.
    N. A. Borisevich, L. B. Vodovatov, G. G. D’yachenko, V. A. Petukhov, and M. A. Semenov, Opt. i Spektr., 89, 249–256 (2000).Google Scholar

Copyright information

© Springer Science+Business Media, Inc. 2007

Authors and Affiliations

  • G. G. D’yachenko
    • 1
  • V. A. Petukhov
    • 1
  • M. A. Semenov
    • 1
  1. 1.P. N. Lebedev Physics InstituteRussian Academy of SciencesMoscow

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