Abstract
Aluminum (Al) coatings, which are found to be dendrites, have been deposited on uranium (U) substrate in ionic liquid via galvanic displacement. Interestingly, a dense Al nano-layer has formed between the Al dendrites and the U substrate. In this work, the growth mechanism of the Al coating has been investigated by ultraviolet–visible spectroscopy, scanning electron microscopy, grazing incidence X-ray diffraction, and electrochemical measurements: the galvanic reaction sees the oxidation of U from the substrate while Al2Cl7− are reduced on its surface, driven by the electrochemical potential difference between Al and U. Furthermore, we have found that the Al nano-layer passivates the uranium surface, which is proved to be the rate limiting step in the galvanic deposition process; the observation of the interface morphology evolution process indicates that this Al nano-layer grows in a three-dimensional mode. This work demonstrates a convenient approach to deposit dense Al nano-layer on U, without any external power source.
Graphical Abstract
Similar content being viewed by others
References
Lee DJ, Lee HS (2006) Microelectron Reliab 46:1194
Liu FM, Green. M (2004) J Mater Chem 14:1526
Neves HP, Kudrle TD, Chen JM, Adams SG, Maharbiz M, Lopatin S, MacDonald NC (1998) MRS Proc 546:139
Yeh JLA, Jiang H, Neves HP, Tien NC (2008) J Microelectromech S 9:281
Shacham-Diamand Y, Sverdlov Y (2000) Microelectron Eng 50:525
Abbott AP, Frisch G, Hartley J, Karim WO, Ryder KS (2015) Prog Nat Sci Mater 25:595
Abbott AP, Frisch G, Ryder KS (2013) Annu Rev Mater Res 43:335
Wang YC, Lin JY, Han Wang C, Huang PL, Lee SL, Chang JK (2014) RSC Adv 4:35298
Falola BD (2015) I. I. Suni. Curr. Opin. Solid State Mater Sci 19:77
DaRosa CP, Iglesia E, Maboudian. R (2008) J Electrochem Soc 155:244
DaRosa CP, Maboudian R, Iglesia. E (2008) J Electrochem Soc 155:70
DaRosa CP, Maboudian R, Iglesia E (2009) Electrochim Acta 54:3270
Abbott AP, Nandhra S, Postlethwaite S, Smith EL, Ryde KS (2007) Phys Chem Chem Phys 9:3735
Lahiri A, Borisenko N, Olschewski M, Gustus R, Zahlbach J, Endres F (2015) Angew Chem Int Ed 54:11870
Jiang YD, Ding JJ, Luo LZ, Shi P, Wang XL (2017) Surf Coat Technol 309:980
Egert CM, Scott. DG (1987) J Vac Sci Technol A 5:2724
Wilkes JS, Levisky JA, Wilson RA, Hussey CL (1982) Inorg Chem 21:1263
Jiang YD, Luo LZ, Wang SF, Bing R, Zhang GK, Wang XL (2018) Appl Surf Sci 427:528
Jiang T, Brym MJC, Dubé G, Lasia A, Brisard GM (2006) Surf Coat Technol 201:1
Falola BD, Suni. II (2014) J Electrochem Soc 161:107
Luo YR (2007) Comprehensive hand book of chemical bond energies. CRC Press, Boca Raton
Johnson AJ, Shreir LL (1965) Corros Sci 5:269
Carraro C, Maboudian R, Magagnin L (2007) Surf Sci Rep 62:499
Landolt D (1987) Electrochim Acta 32:1
Acknowledgements
The authors would like to thank Prof. Ling, Prof. Zhang, Colleague Xiandong Meng and Anyi Yin for technical support. And this work is supported by the National Natural Science Foundation of China (No. 11404295), National Key Scientific Apparatus Development of Special Item of China (No. 2012YQ130125) and the Disipline Development Foundation of China Academy of Engineering and Physics (No. 2015B0301065).
Author information
Authors and Affiliations
Corresponding author
Rights and permissions
About this article
Cite this article
Jiang, Y., Fang, L., Luo, L. et al. Deposition mechanism of aluminum on uranium in AlCl3-1-ethyl-3-methylimidazolium chloride ionic liquid by galvanic displacement. J Appl Electrochem 48, 827–834 (2018). https://doi.org/10.1007/s10800-018-1204-4
Received:
Accepted:
Published:
Issue Date:
DOI: https://doi.org/10.1007/s10800-018-1204-4