Abstract
Poly(3,4-ethylenedioxythiophene) nanowires (nw-PEDOT), between 6.7–13.8 nm diameter, were obtained by electrochemical methods utilizing modified electrodes with silicon oxide as a template to afford a Pt/nw-PEDOT electrode. Dopamine electro-polymerization was next accomplished upon this electrode (Pt/nw-PEDOT/PDA). The Pt/nw-PEDOT/PDA assembly is capable of hindering interfering signals such as those from ascorbic and uric acid, enabling thus the selective detection of dopamine. Amperometric determination studies allowed limit of detection and limit of quantification limits of 0.47 and 1.59 µM, respectively, to be established. These limits were lower than those obtained with the same conducting polymer but without a nanowire structure.
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Lin K, Yin C, Chen S-M (2011) Simultaneous determination of AA, DA, and UA based on bipolymers by electropolymerization of luminol and 3,4-ethylenedioxythiophene monomers. Int J Electrochem Sci 6:3951–3965
Safavi A, Maleki N, Moradlou O, Tajabadi F (2006) Simultaneous determination of dopamine, ascorbic acid, and uric acid using carbon ionic liquid electrode. Anal Biochem 359:224–229
Kim B, Son S, Lee K, Yang H, Kwak J (2012) Dopamine detection using the selective and spontaneous formation of electrocatalytic poly(dopamine) films on indium-tin oxide electrodes. Electroanalysis 24:993–996
Luczak T (2008) Electrocatalytic application of an overoxidized dopamine film prepared on a gold electrode surface to selective epinephrine sensing. Electroanalysis 20:1317–1322
Luczak T (2008) Preparation and characterization of the dopamine film electrochemically deposited on a gold template and its applications for dopamine sensing in aqueous solution. Electrochim Acta 53:5725–5731
Chang H, Dong IK, Yu CP (2006) Electrochemically degraded dopamine film for the determination of dopamine. Electroanalysis 18:1578–1583
Salgado R, del Rio R, del Valle MA, Armijo F (2013) Selective electrochemical determination of dopamine, using a poly(3,4-ethylenedioxythiophene)/polydopamine hybrid film modified electrode. J Electroanal Chem 704:130–136
Yoon H, Chang M, Jang J (2007) Formation of 1D poly(3,4-ethylenedioxythiophene) nanomaterials in reverse microemulsions and their application to chemical sensors. Adv Funct Mater 17:431–436
Xu G, Li B, Cui XT, Ling L, Luo X (2013) Electrodeposited conducting polymer PEDOT doped with pure carbon nanotubes for the detection of dopamine in the presence of ascorbic acid. Sens Actuators B Chem 188:405–410
Palanisamy S, Ku S, Chen S-M (2013) Dopamine sensor based on a glassy carbon electrode modified with a reduced graphene oxide and palladium nanoparticles composite. Microchim Acta 180:1037–1042
Yang S, Li G, Yin Y, Yang R, Li J, Qu L (2013) Nano-sized copper oxide/multi-wall carbon nanotube/Nafion modified electrode for sensitive detection of dopamine. J Electroanal Chem 703:45–51
Song M-J, Lee S-K, Kim J-H, Lim D-S (2012) Dopamine sensor based on a boron-doped diamond electrode modified with a polyaniline/Au nanocomposites in the presence of ascorbic acid. Anal Sci 28:583–588
Lu H-H, Lin C-Y, Hsiao T-C, Fang Y-Y, Ho K-C, Yang D, Lee C-K, Hsu S-M, Lin C-W (2009) Electrical properties of single and multiple poly(3,4-ethylenedioxythiophene) nanowires for sensing nitric oxide gas. Anal Chim Acta 640:68–74
Seung IC, Sang BL (2008) Fast electrochemistry of conductive polymer nanotubes: synthesis, mechanism, and application. Acc Chem Res 41:699–707
Long YZ, Duvail JL, Chen ZJ, Jin AZ, Gu CZ (2009) Electrical properties of isolated poly(3,4-ethylenedioxythiophene) nanowires prepared by template synthesis. Polym Adv Technol 20:541–544
Liu R, Lee SB (2008) MnO2/poly(3,4-ethylenedioxythiophene) coaxial nanowires by one-step coelectrodeposition for electrochemical energy storage. J Am Chem Soc 130:2942–2943
Duvail JL, Long Y, Retho P, Louarn G, de Dauginet Pra L, Demoustier-Champagne S (2008) Enhanced electroactivity and electrochromism in PEDOT nanowires. Mol Cryst Liq Cryst 485:835–842
Wang Y, Coti KK, Wang J, Alam MM, Shyue J-J, Lu W, Padture NP, Tseng H-R (2007) Individually addressable crystalline conducting polymer nanowires in a microelectrode sensor array. Nanotechnology 18:424021
Samitsu S, Shimomura T, Ito K, Fujimori M, Heike S, Hashizume T (2005) Conductivity measurements of individual poly(3,4-ethylenedioxythiophene)/poly(styrenesulfonate) nanowires on nanoelectrodes using manipulation with an atomic force microscope. Appl Phys Lett 86:1–3
Hamedi M, Herland A, Karlsson RH, Lnganäs O (2008) Electrochemical devices made from conducting nanowire networks self-assembled from amyloid fibrils and alkoxysulfonate PEDOT. Nano Lett 8:1736–1740
Walcarius A, Sibottier E, Etienne M, Ghanbaja J (2007) Electrochemically assisted self-assembly of mesoporous silica thin films. Nat Mater 6:602–608
del Valle MA, Gacitúa M, Díaz FR, Armijo F, del Río R (2009) Electrosynthesis of polythiophene nanowires via mesoporous silica thin film templates. Electrochem Commun 11:2117–2120
del Valle MA, Gacitua M, Diaz FR, Armijo F, Soto JP (2012) Electro-synthesis and characterization of polythiophene nano-wires/platinum nano-particles composite electrodes. Study of formic acid electro-catalytic oxidation. Electrochim Acta 71:277–282
East GA, del Valle MA (2000) Easy-to-make Ag/AgCl reference electrode. J Chem Educ 77:97
del Valle MA, Camarada MB, Díaz F, East GA (2008) Correlation between morphology and NGM of 3,4-ethylenedioxythiophene (EDOT) in acetonitrile. e-Polymers (No. 072) 8:839–850
Arteaga GC, del Valle MA, Antilén M, Romero M, Ramos A, Hernández L, Arevalo MC, Pastor E, Louarn G (2013) Nucleation and growth mechanism of electro-synthesized poly(pyrrole) on steel. Int J Electrochem Sci 8:4120–4130
Romero M, del Valle MA, del Río R, Díaz FR, Armijo F, Dalchiele EA (2013) Temperature effect on nucleation and growth mechanism of poly(o-anisidine) and poly(aniline) electro-synthesis. J Electrochem Soc 160:G125–G134
del Valle MA, Salgado R, Armijo F (2014) PEDOT nanowires and platinum nanoparticles modified electrodes to be assayed in formic acid electro-oxidation. Int J Electrochem Sci 9:1557–1564
Acknowledgments
The authors kindly acknowledge the financial support through Project FONDECYT Nr. 1110041 and 1141158. R. Salgado thanks CONICYT Scholarship 2010, Folio 63,100,053.
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Salgado, R., del Valle, M.A., Duran, B.G. et al. Optimization of dopamine determination based on nanowires PEDOT/polydopamine hybrid film modified electrode. J Appl Electrochem 44, 1289–1294 (2014). https://doi.org/10.1007/s10800-014-0728-5
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DOI: https://doi.org/10.1007/s10800-014-0728-5