Journal of Applied Electrochemistry

, Volume 44, Issue 9, pp 1069–1074 | Cite as

Facile microwave synthesis of CoFe2O4 spheres and their application as an anode for lithium-ion batteries

  • Sukeun Yoon
Research Article
Part of the following topical collections:
  1. Batteries


CoFe2O4 spheres were synthesized using a microwave-hydrothermal reaction and characterized by X-ray diffraction, electron microscopy, and electrochemical analysis. This simple synthesis method led to a uniform dispersion of nanosized building blocks in the spheres, which exhibit significantly improved cycling performance and rate capability in lithium cells. The excellent electrochemical performances of CoFe2O4 sphere are attributed to an increased lithium wetting property at the electrode–electrolyte interface, facile lithium-ion diffusion, and better alleviation of the structure pulverization during charge–discharge process.


Lithium-ion batteries Anode CoFe2O4 Microwave-hydrothermal reaction 



This work was supported by the Korea Institute of Energy Research (No. GP2012-0024-03).


  1. 1.
    Gudiksen MS, Lauhon LJ, Wang J, Smith DC, Lieber CM (2002) Growth of nanowire superlattice structures for nanoscale photonics and electronics. Nature 415:617–620CrossRefGoogle Scholar
  2. 2.
    Pacholski C, Kornowski A, Weller H (2002) Self-assembly of ZnO: from nanodots to nanorods. Angew Chem Int Ed 41:1188–1191CrossRefGoogle Scholar
  3. 3.
    Redl FX, Cho KS, Murray CB, O’Brien S (2003) Three-dimensional binary superlattices of magnetic nanocrystals and semiconductor quantum dots. Nature 423:968–971CrossRefGoogle Scholar
  4. 4.
    Bruce PG, Scrosati B, Tarascon JM (2008) Nanomaterials for rechargeable lithium batteries. Angew Chem Int Ed 47:2930–2946CrossRefGoogle Scholar
  5. 5.
    Yang LC, Gao QS, Zhang YH, Tang Y, Wu YP (2008) Tremella-like molybdenum dioxide consisting of nanosheets as an anode material for lithium ion battery. Electrochem Commun 10:118–122CrossRefGoogle Scholar
  6. 6.
    Xia XH, Tu JP, Xiang JY, Huang XH, Wang XL, Zhao XB (2010) Hierarchical porous cobalt oxide array films prepared by electrodeposition through polystyrene sphere template and their applications for lithium ion batteries. J Power Sources 195:2014–2022CrossRefGoogle Scholar
  7. 7.
    Li CC, Li QH, Chen LB, Wang TH (2011) Topochemical synthesis of cobalt oxide nanowire arrays for high performance binderless lithium ion batteries. J Mater Chem 21:11867–11872CrossRefGoogle Scholar
  8. 8.
    Yoon S, Manthiram A (2011) Hollow core-shell mesoporous TiO2 spheres for lithium ion storage. J Phys Chem C 115:9410–9416CrossRefGoogle Scholar
  9. 9.
    Zhu X, Zhu Y, Murali S, Stoller MD, Ruoff RS (2011) Reduced graphene oxide/tin oxide composite as an enhanced anode material for lithium ion batteries prepared by homogenous coprecipitation. J Power Sources 196:6473–6477CrossRefGoogle Scholar
  10. 10.
    Yim CH, Baranova EA, Courtel FM, Abu-Lebdeh Y, Davidson IJ (2011) Synthesis and characterization of macroporous tin oxide composite as an anode material for Li-ion batteries. J Power Sources 196:9731–9736CrossRefGoogle Scholar
  11. 11.
    Li MY, Wang Y, Liu CL, Gao H, Dong WS (2012) Iron oxide/carbon microsphere lithium-ion battery electrode with high capacity and good cycling stability. Electrochim Acta 67:187–193CrossRefGoogle Scholar
  12. 12.
    Ding Y, Li J, Zhao Y, Guan L (2012) Direct synthesis of iron oxide nanoparticles on an iron current collector as binder-free anode materials for lithium-ion batteries. Mater Lett 81:105–107CrossRefGoogle Scholar
  13. 13.
    Ryu MH, Jung KN, Shin KH, Han KS, Yoon S (2013) High performance N-doped mesoporous carbon decorated TiO2 nanofibers as anode materials for lithium-ion batteries. J Phys Chem C 117:8092–8098CrossRefGoogle Scholar
  14. 14.
    Choi SH, Kang YC (2014) Crumpled graphene-molybdenum oxide composite powders: preparation and application in lithium-ion batteries. ChemSusChem 7:523–528CrossRefGoogle Scholar
  15. 15.
    Davis ME (2002) Ordered porous materials for emerging applications. Nature 417:813–821CrossRefGoogle Scholar
  16. 16.
    Goltner CG, Smarsly B, Berton B, Antonietti M (2001) On the microporous nature of mesoporous molecular sieves. Chem Mater 13:1617–1624CrossRefGoogle Scholar
  17. 17.
    Lavela P, Tirado JL (2007) NiFe2O4 synthesized by sol-gel procedures for their use as anode materials for Li ion batteries. J Power Sources 172:379–387CrossRefGoogle Scholar
  18. 18.
    Sharma Y, Sharma N, Subba Rao GV, Chowdari BVR (2008) Studies on spinel cobaltites, FeCo2O4 and MgCo2O4 as anodes for Li-ion batteries. Solid State Ionics 179:587–597CrossRefGoogle Scholar
  19. 19.
    Li ZH, Zhao TP, Zhan XY, Gao DS, Xiao QZ, Lei GT (2010) High capacity three-dimensional ordered macroporous CoFe2O4 as anode material for lithium ion batteries. Electrochim Acta 55:4594–4598CrossRefGoogle Scholar
  20. 20.
    Liu S, Xie J, Fang C, Cao G, Zhu T, Zhao X (2012) Self-assembly of a CoFe2O4/graphene sandwich by a controllable and general route: towards a high-performance anode for Li-ion batteries. J Mater Chem 22:19738–19743CrossRefGoogle Scholar
  21. 21.
    Zhang Z, Wang Y, Zhang M, Tan Q, Lv X, Zhong Z, Su F (2013) Mesoporous CoFe2O4 nanospheres cross-linked by carbon nanotubes as high-performance anodes for lithium-ion batteries. J Mater Chem A 1:7444–7450CrossRefGoogle Scholar
  22. 22.
    Lee SH, Yu SH, Lee JE, Jin A, Lee DJ, Lee N, Jo H, Shin K, Ahn TY, Kim YW, Choe H, Sung YE, Hyeon T (2013) Self-assembled Fe3O4 nanoparticle clusters as high-performance anodes for lithium ion batteries via geometric confinement. Nano Lett 13:4249–4256CrossRefGoogle Scholar
  23. 23.
    Lei C, Han F, Sun Q, Li WC, Lu AH (2014) Confined nanospace pyrolysis for the fabrication of coaxial Fe3O4@C hollow particles with a penetrated mesochannel as a superior anode for Li-ion batteries. Chem Eur J 20:139–145CrossRefGoogle Scholar
  24. 24.
    Xiong QQ, Tu JP, Shi SJ, Liu XY, Wang XL, Gu CD (2014) Ascorbic acid-assisted synthesis of cobalt ferrite (CoFe2O4) hierarchical flower-like microspheres with enhanced lithium storage properties. J Power Sources 256:153–159CrossRefGoogle Scholar
  25. 25.
    Fu X, Chen D, Wang M, Yang Y, Wu Q, Ma J, Zhao X (2014) Synthesis of porous CoFe2O4 octahedral structures and studies on electrochemical Li storage behavior. Electrochim Acta 116:164–169CrossRefGoogle Scholar
  26. 26.
    Zhu G, Pan L, Xu T, Sun Z (2011) One-step synthesis of CdS sensitized TiO2 photoanodes for quantum dot-sensitized solar cells by microwave assisted chemical bath deposition method. ACS Appl Mater Interfaces 3:1472–1478CrossRefGoogle Scholar
  27. 27.
    Shi Y, Chou SL, Wang JZ, Wexler D, Li HJ, Liu HK, Wu Y (2012) Graphene wrapped LiFePO4/C composites as cathode materials for Li-ion batteries with enhanced rate capability. J Mater Chem 22:16465–16470CrossRefGoogle Scholar
  28. 28.
    Weppner W, Huggins RA (1977) Determination of the kinetic parameters of mixed-conducting electrodes and application to the system Li3Sb. J Electrochem Soc 124:1569–1578CrossRefGoogle Scholar
  29. 29.
    Yoon S, Manthiram A (2009) Sb–MOx–C (M = Al, Ti, or Mo) nanocomposite anodes for lithium-ion batteries. Chem Mater 21:3898–3904CrossRefGoogle Scholar

Copyright information

© Springer Science+Business Media Dordrecht 2014

Authors and Affiliations

  1. 1.Division of Advanced Materials EngineeringKongju National UniversityChungnamRepublic of Korea

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