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Journal of Applied Electrochemistry

, Volume 43, Issue 2, pp 209–215 | Cite as

Emission spectra and transient photovoltage in dye-sensitized solar cells under stress tests

  • M. Giustini
  • D. Angelone
  • M. Parente
  • D. Dini
  • F. Decker
  • A. Lanuti
  • A. Reale
  • T. Brown
  • A. di Carlo
Original Paper

Abstract

Dye-sensitized solar cells have been tested before, during, and after stress tests performed either under intense Xe-lamp illumination (equivalent to 1 sun up to 2.5 sun) or under thermal cycles between room T and 80 °C. In-situ emission spectra and transient photovoltage decay curves have been taken to monitor the cell aging conditions. Incipient degradation phenomena in aged cells can be detected by changes in emission intensity, maximum photovoltage and in the time constant of photovoltage decay. UV-filtering of the Xe beam can prevent such cell degradation, provided the cell overheating is avoided.

Keywords

Dye-sensitized solar cell (DSC) Solar energy conversion Sensitizer emission Photovoltage transients Aging Accelerated tests 

Notes

Acknowledgments

M. G. thanks the CSGI for the partial financial support. The authors wish to thank both Referees for their precious suggestions that increased the readability of the manuscript.

Supplementary material

10800_2012_484_MOESM1_ESM.docx (4.1 mb)
Supplementary material 1 (DOCX 4200 kb)

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Copyright information

© Springer Science+Business Media Dordrecht 2012

Authors and Affiliations

  • M. Giustini
    • 1
    • 2
  • D. Angelone
    • 1
  • M. Parente
    • 1
  • D. Dini
    • 1
  • F. Decker
    • 1
  • A. Lanuti
    • 3
  • A. Reale
    • 3
  • T. Brown
    • 3
  • A. di Carlo
    • 3
  1. 1.Department of ChemistryUniversity of Roma “La Sapienza”RomeItaly
  2. 2.CSGI c/o Department of ChemistryUniversity of BariBariItaly
  3. 3.Department of Electronic Engineering, CHOSE–Centre for Hybrid and Organic Solar EnergyUniversity of Rome Tor VergataRomeItaly

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