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Inorganic Materials

, Volume 41, Issue 10, pp 1067–1072 | Cite as

Crystal Structure of Nb5Si3 − xP0.5 + x (x = 0–0.5)

  • Ya. F. Lomnytska
  • S. V. Oryshchyn
  • Yu. B. Kuz'ma
  • R. Guerin
Article
  • 34 Downloads

Abstract

The structure of the ternary compound Nb5Si3 − xP0.5 + x (x = 0–0.5) is determined by single-crystal x-ray diffraction: sp. gr. P63mc, a = 1.32350(5) nm, c = 0.52954(1) nm; R F = 0.028, Rw = 0.081 for 547 reflections with F hkl > 4.0σ(F hkl ). Relations between the structure of Nb5Si3 − xP5 + x, the Mn5Si3 structure type, and its derivatives are discussed.

Keywords

Reflection Crystal Structure Inorganic Chemistry Structure Type Ternary Compound 
These keywords were added by machine and not by the authors. This process is experimental and the keywords may be updated as the learning algorithm improves.

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REFERENCES

  1. 1.
    Lomnytska, Ya.F. and Koval', L.V., Phase Relations in the Nb-Si-P and Ta-Si-P Systems, Zh. Neorg. Khim., 1996, vol. 41, no.11, pp. 1925–1927.Google Scholar
  2. 2.
    Aksel'rud, L.G., Grin, Yu.N., Pecharsky, V.K., and Zavalij, P.Yu., CSD97—Universal Program Package for Single Crystal and Powder Data Treatment, Version no. 7, 1997.Google Scholar
  3. 3.
    Emsley, J., Die Elemente, Berlin: Gruyter, 1994.Google Scholar
  4. 4.
    Kripyakevich, P.I., Strukturnye tipy intermetallicheskikh soedinenii (Structure Types of Intermetallic Compounds), Moscow: Nauka, 1977.Google Scholar

Copyright information

© MAIK "Nauka/Interperiodica" 2005

Authors and Affiliations

  • Ya. F. Lomnytska
    • 1
  • S. V. Oryshchyn
    • 1
  • Yu. B. Kuz'ma
    • 1
  • R. Guerin
    • 2
  1. 1.Franko National UniversityLvivUkraine
  2. 2.Laboratoire de Chimie du Solide et Inorganique Moleculaire, UMR CNRS 6511Rennes CedexFrance

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