Skip to main content
Log in

Thermodynamic assessment of high-temperature oxidation of Fe—Cr alloys in air

  • Published:
Inorganic Materials Aims and scope

Abstract

A thermodynamic technique is proposed for assessing the variation of composition with depth in systems graded in composition. The technique is used to evaluate the compositions of scales forming on Fe, Cr, and Fe—Cr alloys during high-temperature oxidation in air. The coexistence of inclusions and extended precipitates of several phases in scales is interpreted in terms of oxidation thermodynamics kinetics.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Similar content being viewed by others

REFERENCES

  1. C. Wagner (1933) ArticleTitleTheory of Tarnishing Process Z. Phys. Chem. B 21 IssueID1/2 25–41

    Google Scholar 

  2. C. Wagner (1959) ArticleTitleReaction Types in the Oxidation of Alloys Z. Electrochem. 63 772–882

    Google Scholar 

  3. R.A. Rapp (1965) ArticleTitleKinetics, Microstructures, and Mechanism of Internal Oxidation, Its Effect and Prevention in High-Temperature Alloy Oxidation Corrosion (Houston) 21 IssueID12 382–400

    Google Scholar 

  4. D.L. Douglass (1995) ArticleTitleA Critique of Internal Oxidation in Alloys during the Post-Wagner Era Oxid. Met. 44 IssueID1/2 81–111

    Google Scholar 

  5. J.L. Meijering (1971) ArticleTitleInternal Oxidation in Alloy Adv. Mater. Sci. 5 1–81

    Google Scholar 

  6. F. Gesmundo Y. Niu (1999) ArticleTitleThe Formation of Two Layers in the Internal Oxidation of Binary Alloys by Two Oxidants in the Absence of External Scales Oxid. Met. 51 IssueID1/2 129–158

    Google Scholar 

  7. D.J. Young (2000) ArticleTitleInternal Oxidation Processes under Non-Ideal Conditions Mater. High Temp. 17 IssueID4 465–470

    Google Scholar 

  8. J. Philibert (1999) ArticleTitleGrain Boundary Diffusion and Oxidation Processes Solid State Ionics 117 7–11

    Google Scholar 

  9. N. Birks G.H. Meier (1983) Introduction to High-Temperature Oxidation of Metals Arnold London

    Google Scholar 

  10. N.A. Vatolin G.K. Moiseev B.G. Trusov (1994) Termodinamicheskoe modelirovanie v vysokotemperaturnykh neorganicheskikh sistemakh Metallurgiya Moscow

    Google Scholar 

  11. O.Yu. Goncharov O.M. Kanunnikova A.A. Shakov S.F. Lomaeva (2001) ArticleTitleComposition of Surface Layers Forming during Preparation of the Amorphous Alloy Fe70Cr15B15 Fiz. Met. Metalloved. 91 IssueID6 64–71

    Google Scholar 

  12. P.A. Labun J. Covington K. Kuroda et al. (1982) ArticleTitleMicrostructural Investigation of the Oxidation of an Fe-3pct Cr Alloy Metall. Trans. A 3 2103–2112

    Google Scholar 

  13. A.I. Kahveci G.E. Welsch (1986) ArticleTitleOxidation of Fe-3 wt % Cr Alloy Oxid. Met. 26 IssueID3/4 213–230

    Google Scholar 

  14. K. Tsuji K. Hirokawa (1996) ArticleTitleNondestructive Depth Profiling of Oxidized Fe-Cr Alloy by the Glancing-Incidence and Takeoff Fluorescence Method Appl. Surf. Sci. 103 451–458

    Google Scholar 

  15. T. Kosaka S. Suzuki H. Inoue et al. (1996) ArticleTitleXPS/GIXS Studies of Thin Oxide Films Formed on Fe-Cr Alloys Appl. Surf. Sci. 103 IssueID1 55–61

    Google Scholar 

  16. Goncharova, N.V. and Makhneva, T.M., Thermodynamic Assessment of Nitrogen Solubility in Fe-Cr Alloys, Fiz. Khim. Obrab. Mater., 2000, no. 1, pp. 81–85.

  17. N.V. Goncharova T.M. Makhneva E.P. Elsukov et al. (1998) ArticleTitleResidual Austenite in the Ferrite Alloy Fe-Cr Fiz. Met. Metalloved. 86 IssueID6 53–58

    Google Scholar 

  18. Tylkin, M.A., Plotnikova, L.P., Semenova, L.M., and Evtushenko, I.D., Effect of High-Temperature Oxidation on the Scale Composition and Steel Structure, Metalloved.Term. Obrab. Met., 1981, no. 3, pp. 44–47.

  19. J. Kučera M. Haiduga K. Strnský (1993) ArticleTitleKrystalografická struktura a chemicke složeni okují vzniklých na povrchu oceli Fe-Cr-C p č 1100°C Kokové Mater. 31 IssueID1 65–75

    Google Scholar 

  20. I. Saeki T. Saito R. Furuichi et al. (1998) ArticleTitleGrowth Process of Protective Oxides Formed on Type 340 and 430 Stainless Steel at 1273 K Corros. Sci. 40 IssueID8 1295–1302

    Google Scholar 

  21. S. Suzuki K. Suzuki (1991) ArticleTitleAES/GDS Characterization of Thin Oxide Films on Fe-Cr Sheet Steels Surf. Interface Anal. 17 551–555

    Google Scholar 

  22. A.A. Baikov (1948) Sobranie trudov Akad. Nauk SSSR Moscow 531–546

    Google Scholar 

  23. G. Eriksson K. Hack (1990) ArticleTitleChemSage—A Computer Program for the Calculation of Complex Chemical Equilibria Metall. Trans. B 21 IssueID6 1013–1023

    Google Scholar 

  24. G.V. Belov (2002) Termodinamicheskoe modelirovanie: metody, algoritmy, programmy Nauchnyi Mir Moscow

    Google Scholar 

  25. L.V. Gurvich I.V. Veits V.A. Medvedev et al. (1978) Termodinamicheskie svoistva individual’nykh veshchestv Nauka Moscow

    Google Scholar 

  26. G.K. Moiseev N.A. Vatolin L.A. Marshuk N.I. Il’inykh (1997) Temperaturnye zavisimosti privedennoi energii Gibbsa nekotorykh neorganicheskikh veshchestv Ural. Otd. Ross. Akad. Nauk Yekaterinburg

    Google Scholar 

  27. I. Barin O. Knacke O. Kubaschewski (1977) Thermochemical Properties of Inorganic Substances Springer Berlin

    Google Scholar 

  28. I. Murris Y.P. Jacob V.A.C. Haanappel M.F. Stroosnijder (2001) ArticleTitleHigh-Temperature Oxidation Behavior of Chromium: Effect of Different Batches Oxid. Met. 55 IssueID3/4 307–331

    Google Scholar 

  29. Y.P. Jacob V.A.C. Haanappel M.F. Stroosnijder et al. (2002) ArticleTitleThe Effect of Gas Composition on the Isothermal Oxidation Behaviour of PM Chromium Corros. Sci. 44 IssueID9 2027–2039

    Google Scholar 

  30. T. Kacsichy K.P. Lieby A. Schaperz O. Schulte (1996) ArticleTitleOxidation of Thin Chromium Nitride Films: Kinetics and Morphology J. Phys.: Condens. Matter 8 IssueID49 10703–10719

    Google Scholar 

  31. Fu-H. Lu H.-Y. Chen (2001) ArticleTitlePhase Changes of CrN Films Annealed at High Temperature under Controlled Atmosphere Thin Solid Films 398 367–373

    Google Scholar 

  32. J.R. Taylor A.T. Dinsdale (1993) ArticleTitleThermodynamic Assessment of the Cr-Fe-O System Z. Metallkd. 84 IssueID5 335–345

    Google Scholar 

  33. I.I. Kositsina I.G. Kabanova (2003) ArticleTitleNitriding Behavior of High-Chromium Alloys Izv. Akad. Nauk, Ser. Fiz. 67 IssueID7 944–947

    Google Scholar 

  34. L. Xiaomei V.E. Henrich (1996) ArticleTitleObservation of Unusual Surface Defect Behavior on Single Crystal Cr2O3 (1012) under Ion Bombardment Solid State Commun. 98 IssueID8 711–715

    Google Scholar 

Download references

Author information

Authors and Affiliations

Authors

Additional information

Translated from Neorganicheskie Materialy, Vol. 40, No. 12, 2004, pp. 1476–1482.

Original Russian Text Copyright © 2004 by Goncharov.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Goncharov, O.Y. Thermodynamic assessment of high-temperature oxidation of Fe—Cr alloys in air. Inorg Mater 40, 1295–1300 (2004). https://doi.org/10.1007/s10789-005-0087-z

Download citation

  • Received:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10789-005-0087-z

Keywords

Navigation