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Solvation Behavior of Glycine, l-Alanine, and l-Valine in Aqueous Solutions of Triammonium Citrate at Different Temperatures with Reference to Speeds of Sound Measurements

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Abstract

The speeds of sound measurements are carried out for investigating the interactions of glycine, l-alanine, and l-valine in \((0.2, 0.4, 0.6, \hbox { and } 0.8)\hbox { mol}{\cdot }\hbox {kg}^{-1}\) solutions of triammonium citrate (TAC) at \(T = (288.15, 298.15, 308.15, \hbox { and } 318.15)\hbox { K}\). The speeds of sound values were used to determine apparent molar isentropic compression (\(\kappa _{\phi ,s})\), partial molar isentropic compression (\(\kappa _{\phi ,s}^0)\), hydration number (\(n_{H})\), standard partial molar isentropic compression of transfer (\(\Delta \kappa _{\phi ,S}^0)\). The pair and triplet interaction coefficients have also been calculated. The results have been discussed in terms of prevailing interactions between amino acids and TAC solutions.

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Acknowledgments

One of the authors (MS) is thankful to The Director and Head, Department of Chemistry, Dr B. R Ambedkar National Institute of Technology, Jalandhar for providing MHRD fellowship.

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Authors and Affiliations

  1. Department of Chemistry, Dr B R Ambedkar National Institute of Technology, Jalandhar, 144 011, Punjab, India

    Harsh Kumar, Meenu Singla & Rajeev Jindal

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  1. Harsh Kumar
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  2. Meenu Singla
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  3. Rajeev Jindal
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Correspondence to Harsh Kumar.

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Kumar, H., Singla, M. & Jindal, R. Solvation Behavior of Glycine, l-Alanine, and l-Valine in Aqueous Solutions of Triammonium Citrate at Different Temperatures with Reference to Speeds of Sound Measurements. Int J Thermophys 37, 21 (2016). https://doi.org/10.1007/s10765-015-2006-0

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  • DOI: https://doi.org/10.1007/s10765-015-2006-0

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