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Solvation Behavior of Glycine, l-Alanine, and l-Valine in Aqueous Solutions of Triammonium Citrate at Different Temperatures with Reference to Speeds of Sound Measurements

  • Harsh Kumar
  • Meenu Singla
  • Rajeev Jindal
Article

Abstract

The speeds of sound measurements are carried out for investigating the interactions of glycine, l-alanine, and l-valine in \((0.2, 0.4, 0.6, \hbox { and } 0.8)\hbox { mol}{\cdot }\hbox {kg}^{-1}\) solutions of triammonium citrate (TAC) at \(T = (288.15, 298.15, 308.15, \hbox { and } 318.15)\hbox { K}\). The speeds of sound values were used to determine apparent molar isentropic compression (\(\kappa _{\phi ,s})\), partial molar isentropic compression (\(\kappa _{\phi ,s}^0)\), hydration number (\(n_{H})\), standard partial molar isentropic compression of transfer (\(\Delta \kappa _{\phi ,S}^0)\). The pair and triplet interaction coefficients have also been calculated. The results have been discussed in terms of prevailing interactions between amino acids and TAC solutions.

Keywords

Amino acids Apparent molar isentropic compression Solute–solvent interaction Speeds of sound Triammonium citrate 

Notes

Acknowledgments

One of the authors (MS) is thankful to The Director and Head, Department of Chemistry, Dr B. R Ambedkar National Institute of Technology, Jalandhar for providing MHRD fellowship.

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Copyright information

© Springer Science+Business Media New York 2016

Authors and Affiliations

  1. 1.Department of ChemistryDr B R Ambedkar National Institute of TechnologyJalandharIndia

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