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Fusion Diagrams in the \(\mathrm{BiBO}_{3}\)–\(\mathrm{YbBO}_{3}\) and \(\mathrm{Bi}_{4}\mathrm{B}_{2}\mathrm{O}_{9}\)–\(\mathrm{YbBO}_{3}\) Systems

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Abstract

A calculation model of the Gibbs energy of ternary oxide compounds from the binary components was used. Thermodynamic properties of \(\mathrm{Yb}_{2} \mathrm{O}_{3}\)–\(\mathrm{Bi}_{2}\mathrm{O}_{3}\)–\(\mathrm{B}_{2}\mathrm{O}_{3}\) ternary systems in the condensed state were calculated. Thermodynamic data of binary and ternary compounds were used to determine the stable sections. The probability of reactions between the corresponding components in the \(\mathrm{Yb}_{2} \mathrm{O}_{3}\)–\(\mathrm{Bi}_{2} \mathrm{O}_{3}\)–\(\mathrm{B}_{2} \mathrm{O}_{3}\) system was estimated. Fusibility diagrams of systems \(\mathrm{BiBO}_{3}\)–\(\mathrm{YbBO}_{3}\) and \(\mathrm{Bi}_{4} \mathrm{B}_{2} \mathrm{O}_{9}\)–\(\mathrm{YbBO}_{3}\) were studied by physical–chemical analysis. The isothermal section of the phase diagram of \(\mathrm{Yb}_{2} \mathrm{O}_{3}\)–\(\mathrm{Bi}_{2} \mathrm{O}_{3}\)–\(\mathrm{B}_{2} \mathrm{O}_{3}\) at 298 K is built, as well as the projection of the liquid surface of \(\mathrm{BiBO}_{3}\)–\(\mathrm{B}_{2} \mathrm{O}_{3}\)–\(\mathrm{YbBO}_{3}\).

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  1. Institute of Chemical Problems, National Academy of Sciences of Azerbaijan, G. Javid ave. 29, Baku, 1143, Azerbaijan

    M. M. Asadov & N. A. Akhmedova

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  1. M. M. Asadov
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  2. N. A. Akhmedova
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Asadov, M.M., Akhmedova, N.A. Fusion Diagrams in the \(\mathrm{BiBO}_{3}\)–\(\mathrm{YbBO}_{3}\) and \(\mathrm{Bi}_{4}\mathrm{B}_{2}\mathrm{O}_{9}\)–\(\mathrm{YbBO}_{3}\) Systems. Int J Thermophys 35, 1749–1756 (2014). https://doi.org/10.1007/s10765-014-1673-6

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