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Dielectric Relaxation of HCl and NaCl Solutions Investigated by Terahertz Time-Domain Spectroscopy

  • Wenchao Qiao
  • Kejian Yang
  • Arne Thoma
  • Thomas Dekorsy
Article

Abstract

We have used Terahertz time-domain spectroscopy (THz-TDS) to investigate the complex dielectric function of water solutions containing different ions. Using HCl and NaCl solutions with different concentrations we study the changes of the dielectric response introduced by the ions. We find a linear increase of the real and imaginary part of the dielectric function compared with pure water with increasing ion concentrations. We use an expanded model for fitting the dielectric function based on a combination of a Debye relation and damped harmonic oscillators for the anions and cations. A good agreement between the model and the experimental results is obtained.

Keywords

Teraherz time-domain spectroscopy Water solution Dielectric function Oscillation 

Notes

Acknowledgments

The authors acknowledge financial support by the Center for Applied Photonics (CAP) and China Scholarship Council (CSC). We also thank M. Bonn, H. J. Bakker, and M. Havenith for fruitful discussions. KY acknowledged the Alexander-von Humboldt foundation for support.

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Copyright information

© Springer Science+Business Media, LLC 2012

Authors and Affiliations

  • Wenchao Qiao
    • 1
  • Kejian Yang
    • 1
  • Arne Thoma
    • 1
  • Thomas Dekorsy
    • 1
  1. 1.Department of Physics and Center for Applied PhotonicsUniversity of KonstanzConstanceGermany

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