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Chemical species of localized fe atoms in solid hydrogen using in-beam mössbauer spectroscopy

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Abstract

The 57Fe Mössbauer spectrum obtained after 57Mn (T1/2 = 1.45 min) implantation of solid hydrogen was measured at 7 K. The spectrum was analyzed as three components, and the chemical species of each component was assigned from the obtained Mössbauer parameters and the results of density functional theory (DFT) calculations. The formation process of chemical species and the oxidation states of Fe atoms produced by β– decay of 57Mn are discussed considering the charge transfer process, in relation to previous emission Mössbauer spectroscopy experiments with 57Co implantation of solid hydrogen at low temperature.

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Acknowledgements

The experiments in this study were performed with the approval of QST HIMAC (Experimental Proposal No. 18H301). This work was financially supported by JSPS KAKENHI Grant-in-Aid for Scientific Research (C) No. 25410062 and No. 16K05012.

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Authors and Affiliations

  1. Grad. Sch. Eng. Sci., University of Electro-Communications, Chofu, Tokyo, 182-8585, Japan

    Yoshio Kobayashi & Masami Sato

  2. RIKEN Nishina Center, RIKEN, Wako, Saitama, 351-0198, Japan

    Yoshio Kobayashi & Takashi Nagatomo

  3. Department of Chemistry, Tokyo University Sci., Shinjuku, Tokyo, 162-8602, Japan

    Yasuhiro Yamada

  4. Div. Arts Sci., International Christian University, Mitaka, Tokyo, 181-8585, Japan

    Michael K. Kubo

  5. Grad. Sch. Sci., Osaka University, Toyonaka, Osaka, 560-0043, Japan

    Mototsugu Mihara

  6. Inst. Sci. Eng., Kanazawa University, Kanazawa, Ishikawa, 920-1192, Japan

    Wataru Sato

  7. Dep. Nat. Sci., Tokyo Denki University, Adachi, Tokyo, 120-8551, Japan

    Jun Miyazaki

  8. Sch. Med., Nihon University, Itabashi, Tokyo, 173-0032, Japan

    Atsushi Okazawa

  9. Nat. Inst. Quantum Sci. Tech. HIMAC, Inage, Chiba, 263-8555, Japan

    Shinji Sato & Atsushi Kitagawa

Authors
  1. Yoshio Kobayashi
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  2. Masami Sato
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  3. Yasuhiro Yamada
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  4. Michael K. Kubo
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  5. Mototsugu Mihara
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  6. Wataru Sato
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  7. Takashi Nagatomo
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  8. Jun Miyazaki
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  9. Atsushi Okazawa
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  10. Shinji Sato
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  11. Atsushi Kitagawa
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Correspondence to Yoshio Kobayashi.

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This article is part of the Topical Collection on Proceedings of the International Conference on Hyperfine Interactions (HYPERFINE 2021), 5-10 September 2021, Brasov, Romania

Edited by Ovidiu Crisan

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Kobayashi, Y., Sato, M., Yamada, Y. et al. Chemical species of localized fe atoms in solid hydrogen using in-beam mössbauer spectroscopy. Hyperfine Interact 243, 13 (2022). https://doi.org/10.1007/s10751-022-01793-3

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  • DOI: https://doi.org/10.1007/s10751-022-01793-3

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