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Mossbauer and Raman spectroscopy study of Y-garnet particles’ magnetic properties tune-up through mechanochemically synthesized precursors

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Abstract

We apply high energy mechanosynthesis in mixtures of Y2O3 and Fe2O3 to form activated nanostructured oxide composites for subsequent temperature treatment with the aim to synthesize single phase functional Y3Fe5O12 garnet particles. Obtained at the same temperature regime but starting from structurally different precursors, garnet particles demonstrate different magnetic behavior. Mossbauer and Raman spectroscopy were applied for a comprehensive characterization on the local atomic scale the influence of the mechanochemically produced precursor’s fine structure formed at different activation duration on the structural and magnetic state of the garnet particles. X-ray diffraction and visualization of fine particles structure by SEM microscopy were supplemented. An intermediate disordered iron oxide phases and orthoferrite YFeO3 rather garnet structure formation at prolonged duration of intense mechanical activation was determined. Magnetic structure of Y3Fe5O12 formed after annealing was dependent on the degree of the oxides interaction in precursors and defects concentrated at the grain boundaries and interfaces. Both applied spectroscopies showed complementary insight into the nature of the local structural disorder at the steps of mechanosynthesis to the mechanism of fine garnet structure formation.

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Acknowledgements

Authors thank Moscow University Program of Development, Siberian Branch of Russian Academy of Science, RFBR 19-52-44003 Russian-Mongolian Joint project for technical and financial support.

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Authors and Affiliations

  1. Physics Faculty, Moscow M.V. Lomonosov State University, Moscow, Russia

    Kiseleva Tatiana, Ivanenko Il’ya & Ilyushin Alexander

  2. Institute of Solid State Chemistry and Mechanochemistry, SB RAS, Novosibirsk, Russia

    Grigoreva Tatiana, Tyapkin Pavel, Devyatkina Evgeniya & Lyakhov Nikolay

  3. Shmidt’ Institute of the Physics of the Earth, RAS, Moscow, 123456, Russia

    Markov Gennadiy

  4. Institute of Physics and Technology, Mongolian Academy of Sciences, 13330, Ulaanbaatar, Mongolia

    Sangaa Deleg

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  1. Kiseleva Tatiana
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Correspondence to Kiseleva Tatiana.

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This article is part of the Topical Collection on Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2021), 5-10 September 2021, Brasov, Romania

Edited by Victor Kuncser

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Tatiana, K., Tatiana, G., Pavel, T. et al. Mossbauer and Raman spectroscopy study of Y-garnet particles’ magnetic properties tune-up through mechanochemically synthesized precursors. Hyperfine Interact 242, 57 (2021). https://doi.org/10.1007/s10751-021-01770-2

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