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Hyperfine Interactions

, 239:12 | Cite as

Tuning spin transitions of iron(II)-dpp systems

  • D. Natke
  • D. Unruh
  • B. Dreyer
  • S. Klimke
  • M. Jahns
  • A. Preiss
  • R. Sindelar
  • G. Klingelhöfer
  • F. Renz
Article
  • 67 Downloads
Part of the following topical collections:
  1. Proceedings of the International Conference on the Applications of the Mössbauer Effect (ICAME 2017), Saint-Petersburg, Russia, 3-8 September 2017

Abstract

Chemical modifications of the yet reported iron(II) compound [Fe(dpp)2(NCS)2]⋅Py (dpp = dipyrido[3,2a:2’3’c]phenazine, Py = pyridine) which shows abrupt spin crossover below room temperature with large hysteresis have been made. The purpose was to stabilize different spin states at room temperature as well as to adjust the spin crossover in temperature and hysteresis width. We modified the bidentate ligand dpp by substituting hydrogens at the phenazine by different functional groups. In addition, we substituted the thiocyanate monodentate ligands by NCSe. The spin states of these compounds have been investigated by Mössbauer spectroscopy at two temperatures and temperature depending IR spectroscopy. These methods indicating that the chemical modifications are influencing the observed spin configuration of the complexes alongside the spin crossover behavior which changed to gradual and incomplete transitions. These promising results offer interesting possibilities for chemical adjustments of the shown spin crossover systems.

Keywords

Spin crossover Hysteresis Iron complexes Mössbauer spectroscopy dpp 

Notes

Acknowledgements

The authors would like to thank and acknowledge financial support from Hannover School for Nanotechnology (hsn), Leibniz Universität Hannover (LUH), Laboratory of Nano and Quantum Engineering (LNQE) and Hochschule Hannover (HsH).

Compliance with Ethical Standards

Conflict of interests

The authors declare that they have no conflict of interest.

Supplementary material

10751_2017_1486_MOESM1_ESM.docx (253 kb)
(DOCX 252 KB)

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Copyright information

© Springer International Publishing AG, part of Springer Nature 2018

Authors and Affiliations

  • D. Natke
    • 1
  • D. Unruh
    • 1
  • B. Dreyer
    • 1
    • 2
  • S. Klimke
    • 1
  • M. Jahns
    • 1
  • A. Preiss
    • 1
  • R. Sindelar
    • 2
  • G. Klingelhöfer
    • 3
  • F. Renz
    • 1
  1. 1.Institute of Inorganic ChemistryLeibniz Universität HannoverHanoverGermany
  2. 2.Faculty IIUniversity of Applied Science and ArtsHanoverGermany
  3. 3.Institut für Anorganische Chemie und Analytische ChemieJohannes-Gutenberg-Universität MainzMainzGermany

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