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Defect-fluorite oxides: Ln (Eu and Gd) Mössbauer study coupled with new defect-crystal-chemistry model

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Abstract

A recently proposed lattice-parameter (a 0(ss)) model for parent fluorite-type MO2-LnO1.5 solid solutions (M4 +   =  Ce and Th; Ln3 +   =  lanthanide) has been extended to more complex LnO1.5-stabilized zirconia (hafnia) (M4 +   =  Zr(Hf)) with pyrochlore-type ordering and its-associated broad a 0(ss) hump, using key Ln (Eu and Gd)-Mössbauer and related local-structure data.

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References

  1. Nakamura, A.: Solid State Ionics 181, 1543 (2010)

    Article  Google Scholar 

  2. Nakamura, A.: Solid State Ionics 181, 1631 (2010)

    Article  Google Scholar 

  3. Otobe, H., Nakamura, A.: SOFC-VI, The Electrochem. Soc. Proc. 99–19, pp. 463–473 (1999)

  4. Nakamura, A., Masaki, N., Otobe, H., Hinatsu, Y., Wang, J., Takeda, M.: Pure Appl. Chem. 79, 1691 (2007)

    Article  Google Scholar 

  5. Wang, J., Takeda, M., Shishido, T.: J. Nucl. Mater. 340, 52 (2005)

    Article  ADS  Google Scholar 

  6. Wang, J., Otobe, H., Nakamura, A., Takeda, M.: J. Solid State Chem. 176, 105 (2003)

    Article  ADS  Google Scholar 

  7. Wang, J., Takeda, M., Nakamura, A.: J. Nucl. Mater. 340, 33 (2005)

    Article  ADS  Google Scholar 

  8. Nakamura, A., Otobe, H., Wang, J., Takeda, M.: J. Phys. Chem. Solids 66, 35 (2005)

    Google Scholar 

  9. Harada, D., Hinatsu, Y., Masaki, N., Nakamura, A.: J. Am. Ceram. Soc. 85, 647–652 (2002)

    Article  Google Scholar 

  10. Masaki, N.M., Otobe, H., Nakamura, A., Guillermo, N.R.D., Izumiyama, Y., Harada, D., Hinatsu, Y.: Hyperfine Interact. C305, 305–308 (2003)

    Google Scholar 

  11. Nakamura, A., Imai, K., Igawa, N., Okamoto, Y., Yamamoto, E., Matsukawa, S., Takahashi, M.: Hyperfine Inter. 207, 67–71 (2012)

    Article  ADS  Google Scholar 

  12. Kawata, K., Maekawa, H., Nemoto, T., Yamamura, T.: Solid State Ionics 177, 1687–1690 (2006)

    Article  Google Scholar 

  13. Maekawa, H., Kawata, K., Yamamura, T., Kawamura, J., Xiong, Y.P., Sakai, N., Yokokawa, H.: Solid State Ionics 180, 313–319 (2009)

    Article  Google Scholar 

  14. Kawada, K.: MS thesis, Graduate School of Engineering Tohoku University (2006)

  15. Moriga, T., Emura, S., Yoshiasa, A., Kikkawa, S., Kanamaru, F., Koto, K.: Solid State Ionics 40–41, 357–361 (1990)

    Article  Google Scholar 

  16. Brown, I.D.: The Chemical Bond in Inorganic Chemistry. International Union of Crystallography Monographs of Crystallography, Oxford Univ. Press, Oxford (2002)

    Google Scholar 

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Authors and Affiliations

  1. Advanced Science Research Center, Japan Atomic Energy Agency, Tokai, Naka, Ibaraki, 319-1195, Japan

    A. Nakamura

  2. Quantum Beam Science Directorate, Japan Atomic Energy Agency, Tokai, Naka, Ibaraki, 319-1195, Japan

    N. Igawa & Y. Okamoto

  3. Dalian Institute of Chemical Physics, Chinese Academy of Science, Dalian, 116023, China

    J. Wang

  4. Department of Chemistry, Hokkaido University, Sapporo, 160-0810, Hokkaido, Japan

    Y. Hinatsu

  5. Department of Chemistry, Toho University, Funabashi, Chiba, 274-8510, Japan

    M. Takahashi & M. Takeda

Authors
  1. A. Nakamura
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  2. N. Igawa
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  3. Y. Okamoto
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  4. J. Wang
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  5. Y. Hinatsu
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  6. M. Takahashi
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  7. M. Takeda
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Corresponding author

Correspondence to A. Nakamura.

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Submitted to Hyperfine Interactions as ISIAME2012 (Dalian) Proceedings paper (invited lecture).

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Nakamura, A., Igawa, N., Okamoto, Y. et al. Defect-fluorite oxides: Ln (Eu and Gd) Mössbauer study coupled with new defect-crystal-chemistry model. Hyperfine Interact 217, 17–26 (2013). https://doi.org/10.1007/s10751-012-0654-z

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  • DOI: https://doi.org/10.1007/s10751-012-0654-z

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