Hyperfine Interactions

, Volume 206, Issue 1–3, pp 51–61 | Cite as

Environmental applications: catalysts and removal or re-cycling of by products

  • Károly Lázár


Some applications of Mössbauer spectroscopy are presented with environmental implications. In particular, catalytic processes are discussed with examples for catalyst immobilisation, for removal of contaminants and for decomposition of harmful compounds. Examples are also presented for processes of recycling of end products.


Environmental applications Catalysts Recycling of by products 


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  1. 1.
    Murad, E., Cashion, J.: Mössbauer Spectroscopy of Environmental Materials and their Industrial Utilization, Kluwer, Boston (2004)CrossRefGoogle Scholar
  2. 2.
    Vértes, A., Czakó-Nagy, I.: Mössbauer spectroscopy and its application to corrosion studies. Electrochim. Acta 34, 721–758 (1989)CrossRefGoogle Scholar
  3. 3.
    Millet, J.-M.M.: Mössbauer specroscopy in heterogeneous catalysis. Adv. Catal. 51, 309–350 (2007)CrossRefGoogle Scholar
  4. 4.
    Lázár, K., M-Szeleczky, A., Notheisz, F., Zsigmond, Á.: Encaged iron phthalocyanine for oxygen transfer; Catalytic and Mössbauer spectroscopy study. Stud. Surf. Sci. Catal. 94, 720–727 (1995)CrossRefGoogle Scholar
  5. 5.
    Zsigmond, Á., Notheisz, F., Szegletes, Z.S., Bäckvall, J.E.: Aerobic oxidations on metal macrocycles encapsulated in zeolites. Stud. Surf. Sci. Catal. 94, 728–735 (1995)CrossRefGoogle Scholar
  6. 6.
    Charlton, J.S., Cordey-Hayes, M., Harris, I.R.: A study of the 119Sn Mössbauer isomer shifts in some platinum-tin and gold-tin alloys. J. Less-Common Met. 20, 105–112 (1970)CrossRefGoogle Scholar
  7. 7.
    Rhodes, W.D., Margitfalvi, J.L., Borbáth, I., Lázár, K., Kovalchuk, V.I., d’Itri, J.L.: Hydrogen-assisted 1,2-dichloroethane dechlorination catalysed by Pt-Sn/SiO2 catalysts of different preparations. J. Catal. 230, 86–97 (2005)CrossRefGoogle Scholar
  8. 8.
    Margitfalvi, J.L., Borbáth, I., Lázár, K., Tfirst, E., Szegedi, Á., Hegedűs, M., Gőbölös, S.: In situ characterization of Sn-Pt/SiO2 catalysts used in low temperature oxidation of CO. J. Catal. 203, 94–103 (2001)CrossRefGoogle Scholar
  9. 9.
    Margitfalvi, J.L., Borbáth, I., Hegedûs, M., Tfirst, E., Gőbölös, S., Lázár, K.: Low-temperature CO oxidation over new types of Sn-Pt/SiO2 catalysts. J. Catal. 196, 200–204 (2000)CrossRefGoogle Scholar
  10. 10.
    Yakovlev, A.L., Zhidomirov, G.M., van Santen, R.A.: DFT calculations on N2O decomposition by binuclear Fe complexes. J. Phys. Chem. B 105, 12297–12302 (2001)CrossRefGoogle Scholar
  11. 11.
    Dubkov, K.A., Ovanesyan, N.S., Shteinman, A.A., Starokon, E.V., Panov, G.I.: Evolution of iron states and formation of α-sites upon activation of FeZSM-5 zeolites. J. Catal. 207, 341–352 (2002)CrossRefGoogle Scholar
  12. 12.
    Taboada, J.B., Overweg, A.R., Koyman, P.J., Arends, I.W.C.E., Mul, G.: Following the evolution of iron from framework to extra-framework positions in isomorphously substituted [Fe,Al]MFI with 57Fe Mössbauer spectroscopy. J. Catal. 231, 56–66 (2005)CrossRefGoogle Scholar
  13. 13.
    Kumar, R., Date, S.K., Bill, E., Trautwein, A.: Mössbauer spectroscopic study of ferrisilicate analog of zeolite BETA. Zeolites 11, 211–213 (1991)CrossRefGoogle Scholar
  14. 14.
    Schwarze, M., Sobalik, Z., Caspary, E.G., Niznansky, D.: Characterization of structure of Fe-species in Fe-ferrierite using Mössbauer spectroscopy. Czechoslov. J. Phys. (Suppl. E), 56, E147–E155 (2006)ADSCrossRefGoogle Scholar
  15. 15.
    Lázár, K., Pozdnyakova, O., Wootsch, A., Fejes, P.: Iron ions in ZSM-5 zeolite: Fe3 +  in framework, Fe2 +  in extra-framework positions in catalytic N2O decomposition. Hyperfine Interact. 167, 779–784 (2006)ADSCrossRefGoogle Scholar
  16. 16.
    Kalló, D., Papp, J.: Wastewater treatment with natural clinoptilolite. Stud. Surf. Sci. Catal. 125, 699–706 (1999)CrossRefGoogle Scholar
  17. 17.
    Egyházy, T., Kovács, J., Fülöp, T., Solymár, K.: Utilisation of bauxite residue by modified metallurgical concept. In: Proceedings of the Institute of Environmental and Chemical Engineering, pp. 77–85. Pannon University, Travaux (2004)Google Scholar

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© Springer Science+Business Media B.V. 2011

Authors and Affiliations

  1. 1.Institute of Isotopes, HASBudapestHungary

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