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Hyperfine Interactions

, Volume 202, Issue 1–3, pp 39–46 | Cite as

Complementary 57Fe and 119Sn Mössbauer study of mechanochemical redox reaction

  • V. Šepelák
  • M. J. Nasr Isfahani
  • M. Myndyk
  • M. Ghafari
  • A. Feldhoff
  • K. D. Becker
Article

Abstract

A non-thermal route to oxide nanocomposites by mechanochemical redox reactions in the α-Fe2O3 + SnO system is presented. The important impact of the work, from the methodology point of view, is the combined application of 57Fe and 119Sn Mössbauer spectroscopies to the study of the mechanically induced redox processes, resulting in the reduction of α-Fe2O3 and the oxidation of SnO. In addition, the obtained product was characterized by X-ray diffraction and transmission electron microscopy.

Keywords

Mechanochemistry Redox reaction Mössbauer spectroscopy 

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Copyright information

© Springer Science+Business Media B.V. 2011

Authors and Affiliations

  • V. Šepelák
    • 1
  • M. J. Nasr Isfahani
    • 2
  • M. Myndyk
    • 3
  • M. Ghafari
    • 1
  • A. Feldhoff
    • 4
  • K. D. Becker
    • 5
  1. 1.Institute of NanotechnologyKarlsruhe Institute of TechnologyEggenstein-LeopoldshafenGermany
  2. 2.Department of Physics, Lenjan BranchIslamic Azad UniversityIsfahanIran
  3. 3.Department of Inorganic ChemistryDresden University of TechnologyDresdenGermany
  4. 4.Institute of Physical Chemistry and ElectrochemistryLeibniz University HannoverHannoverGermany
  5. 5.Institute of Physical and Theoretical ChemistryBraunschweig University of TechnologyBraunschweigGermany

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