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Complementary 57Fe and 119Sn Mössbauer study of mechanochemical redox reaction

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Abstract

A non-thermal route to oxide nanocomposites by mechanochemical redox reactions in the α-Fe2O3 + SnO system is presented. The important impact of the work, from the methodology point of view, is the combined application of 57Fe and 119Sn Mössbauer spectroscopies to the study of the mechanically induced redox processes, resulting in the reduction of α-Fe2O3 and the oxidation of SnO. In addition, the obtained product was characterized by X-ray diffraction and transmission electron microscopy.

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References

  1. Carey Lea, M.: Am. J. Sci. 43, 527 (1892)

    Google Scholar 

  2. Avvakumov, E., Senna, M., Kosova, N.: Soft Mechanochemical Synthesis: A Basis for New Chemical Technologies. Kluwer, Boston (2001)

    Google Scholar 

  3. Boldyrev, V.V.: Russ. Chem. Rev. 75, 177 (2006)

    Article  ADS  Google Scholar 

  4. Delogu, F., Mulas, G.: Experimental and Theoretical Studies in Modern Mechanochemistry. Transworld Research Network, Kerala (2010)

    Google Scholar 

  5. Šepelák, V., Bergmann, I., Indris, S., Feldhoff, A., Hahn, H., Becker, K.D., Grey, C.P., Heitjans, P.: J. Mater. Chem. 21, 8332 (2011). doi:10.1039/c0jm03721d

    Article  Google Scholar 

  6. Düvel, A., Wilkening, M., Uecker, R., Wegner, S., Šepelák, V., Heitjans, P.: Phys. Chem. Chem. Phys. 12, 11251 (2010)

    Article  Google Scholar 

  7. Šepelák, V., Becker, K.D., Bergmann, I., Suzuki, S., Indris, S., Feldhoff, A., Heitjans, P., Grey, C.P.: Chem. Mater. 21, 2518 (2009)

    Article  Google Scholar 

  8. Justin Joseyphus, R., Narayanasamy, A., Sivakumar, N., Guyot, M., Krishnan, R., Ponpandian, N., Chattopadhyay, K.: J. Magn. Magn. Mater. 272–276, 2257 (2004)

    Article  Google Scholar 

  9. Wei, Y., Yan, J., Lu, S., Li, X.: J. Environ. Sci. 21, 1761 (2009)

    Article  Google Scholar 

  10. Šepelák, V., Menzel, M., Becker, K.D., Krumeich, F.: J. Phys. Chem. B 106, 6672 (2002)

    Article  Google Scholar 

  11. Takacs, L.: Nanostruct. Mater. 2, 241 (1993)

    Article  Google Scholar 

  12. Basset, D., Matteazzi, P., Miani, F., Le Caër, G.: Hyperfine Interact. 95, 2235 (1994)

    Article  ADS  Google Scholar 

  13. Tokomitsu, K.: Solid State Ionics 101–103, 25 (1997)

    Google Scholar 

  14. Kerr, A., Welham, N.J., Willis, P.E.: Nanostruct. Mater. 11, 233 (1999)

    Article  Google Scholar 

  15. Goya, G.F., Rechenberg, H.R.: J. Phys. Condens. Matter 12, 10579 (2000)

    Article  ADS  Google Scholar 

  16. Grigoryeva, T.F., Novakova, A.A., Kiseleva, T.Y., Barinova, A.P., Ancharov, A.I., Talako, T.L., Vorsina, I.A., Becker, K.D., Šepelák, V., Tsybulya, S.V., Bulavchenko, O.A., Lyakhov, N.Z.: J. Phys.: Conf. Ser. 144, 012076 (2009)

    Article  ADS  Google Scholar 

  17. Kano, J., Kobayashi, E., Tongamp, W., Miyagi, S., Saito, F.: J. Alloy. Compd. 484, 422 (2009)

    Article  Google Scholar 

  18. Iwasaki, T., Sato, N., Kosaka, K., Watano, S., Yanagida, T., Kawai, T.: J. Alloy. Compd. 509, L34 (2011)

    Article  Google Scholar 

  19. Baláž, P., Takacs, L., Godoèíková, E., Škorvánek, I., Kováè, J., Choi W.S.: J. Alloy. Compd. 434–435, 773 (2007)

    Google Scholar 

  20. Ding, J., Tsuzuki, T., McCormick, P.G., Street, R.: J. Magn. Magn. Mater. 162, 271 (1996)

    Article  ADS  Google Scholar 

  21. Setoudeh, N., Welham, N.J.: Int. J. Miner. Process. 98, 214 (2011). doi:10.1016/j.minpro.2010.12.002

    Article  Google Scholar 

  22. Welham, N.J.: J. Alloy. Compd. 274, 303 (1998)

    Article  Google Scholar 

  23. Welham, N.J.: Mater. Sci. Eng. A 248, 230 (1998)

    Article  Google Scholar 

  24. Takacs, L.: Mater. Lett. 13, 119 (1992)

    Article  Google Scholar 

  25. Goya, G.F., Rechenberg, H.R., Jiang, J.Z.: J. Appl. Phys. 84, 1101 (1998)

    Article  ADS  Google Scholar 

  26. Shi, Y., Ding, J.: J. Appl. Phys. 90, 4078 (2001)

    Article  ADS  Google Scholar 

  27. Menzel, M., Šepelák, V., Becker, K.D.: Solid State Ionics 141–142, 663 (2001)

    Article  Google Scholar 

  28. Yang, H., McCormick, P.G.: J. Solid State Chem. 107, 258 (1993)

    Article  ADS  Google Scholar 

  29. Šepelák, V., Steinike, U., Uecker, D.C., Wißmann, S., Becker, K.D.: J. Solid State Chem. 135, 52 (1998)

    Article  ADS  Google Scholar 

  30. Muroi, M., Street, R., McCormick, P.G., Amighian, J.: Phys. Rev. B 63, 184414 (2001)

    Article  ADS  Google Scholar 

  31. Šepelák, V., Feldhoff, A., Heitjans, P., Krumeich, F., Menzel, D., Litterst, F.J., Bergmann, I., Becker, K.D.: Chem. Mater. 18, 3057 (2006)

    Article  Google Scholar 

  32. Šepelák, V., Bergmann, I., Feldhoff, A., Heitjans, P., Krumeich, F., Menzel, D., Litterst, F.J., Campbell, S.J., Becker, K.D.: J. Phys. Chem. C 111, 5026 (2007)

    Article  Google Scholar 

  33. Berchmans, L.J., Myndyk, M., Da Silva, K.L., Feldhoff, A., Šubrt, J., Heitjans, P., Becker, K.D., Šepelák, V.: J. Alloy. Compd. 500, 68 (2010)

    Article  Google Scholar 

  34. Lagarec, K., Rancourt, D.G.: Recoil - Mössbauer Spectral Analysis Software for Windows. University of Ottawa, Ottawa, ON (1998)

    Google Scholar 

  35. Joint Committee on Powder Diffraction Standards (JCPDS) Powder Diffraction File (PDF): International Centre for Diffraction Data, Newton Square, PA (2004)

  36. Kaczmarek, W.A., Ninham, B.W.: IEEE Trans. Magn. 30, 732 (1994)

    Article  ADS  Google Scholar 

  37. Campbell, S.J., Kaczmarek, W.A., Wang, G.M.: Nanostruct. Mater. 6, 735 (1995)

    Article  Google Scholar 

  38. Zdujić, M., Jovalekić, Ć., Karanović, L., Mitrić, M.: Mater. Sci. Eng. A 262, 204 (1999)

    Article  Google Scholar 

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Authors and Affiliations

  1. Institute of Nanotechnology, Karlsruhe Institute of Technology, Herrmann-von-Helmholtz-Platz 1, 76344, Eggenstein-Leopoldshafen, Germany

    V. Šepelák & M. Ghafari

  2. Department of Physics, Lenjan Branch, Islamic Azad University, Isfahan, Iran

    M. J. Nasr Isfahani

  3. Department of Inorganic Chemistry, Dresden University of Technology, Mommsenstrasse 6, 01062, Dresden, Germany

    M. Myndyk

  4. Institute of Physical Chemistry and Electrochemistry, Leibniz University Hannover, Callinstrasse 33A, 30167, Hannover, Germany

    A. Feldhoff

  5. Institute of Physical and Theoretical Chemistry, Braunschweig University of Technology, Hans-Sommer-Strasse 10, 38106, Braunschweig, Germany

    K. D. Becker

Authors
  1. V. Šepelák
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  2. M. J. Nasr Isfahani
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  3. M. Myndyk
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  4. M. Ghafari
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  5. A. Feldhoff
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  6. K. D. Becker
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Corresponding author

Correspondence to V. Šepelák.

Additional information

V. Šepelák is on leave from Slovak Academy of Sciences, 04353 Košice, Slovakia.

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Šepelák, V., Nasr Isfahani, M.J., Myndyk, M. et al. Complementary 57Fe and 119Sn Mössbauer study of mechanochemical redox reaction. Hyperfine Interact 202, 39–46 (2011). https://doi.org/10.1007/s10751-011-0358-9

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  • DOI: https://doi.org/10.1007/s10751-011-0358-9

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