Hyperfine Interactions

, Volume 186, Issue 1–3, pp 39–52 | Cite as

Iron speciation in fault gouge from the Ushikubi fault zone central Japan

  • Guodong Zheng
  • Bihong Fu
  • Yoshio Takahashi
  • Masaaki Miyahara
  • Akihito Kuno
  • Mutoyuki Matsuo
  • Yukari Miyashita


Chemical species of iron and sulfur were measured using 57Fe Mössbauer spectroscopy and X-ray near edge structure, respectively, for the fault gouge samples collected from two sites along the ENE-WSW trending Ushikubi fault zone in central Japan. These gouge samples have distinguishable variations in their physical properties such as surface color and structure and these features are also reflected by the chemical speciation of iron and sulfur. Newly formed minerals, including calcite, dolomite, siderite, iron sulfide and pyrite, have close relation to the colors of fault gouge and respective to the geochemical environment within the fault zone. In addition, the variations in iron and sulfur species may have significance to evaluate the redox conditions in the fractures and furthermore to estimate the history and activity of the faults. Generally there is observacious enrichment of reducing species of iron and sulfur as well as chlorite in the relatively younger fracture, indicating favorable connection pathway with deep position and the fault zone is active. On the other hand, the stable fracture with a longer history is relatively enriched in ferric iron species and almost no sulfur in the gouge. These results from iron and sulfur speciation have a good agreement with evidence indicated by 14C dating from this fault zone.


Fault gouge Redox condition Iron and sulfur speciation Ushikubi fault Japan 


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© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  • Guodong Zheng
    • 1
    • 2
  • Bihong Fu
    • 3
  • Yoshio Takahashi
    • 2
  • Masaaki Miyahara
    • 2
    • 4
  • Akihito Kuno
    • 5
  • Mutoyuki Matsuo
    • 5
  • Yukari Miyashita
    • 6
  1. 1.Key Laboratory of Gas GeochemistryInstitute of Geology and Geophysics, CASLanzhouChina
  2. 2.Department of Earth and Planetary Systems, Graduate School of ScienceHiroshima UniversityHigashi HiroshimaJapan
  3. 3.State Key Laboratory of Lithospheric EvolutionInstitute of Geology and Geophysics, CASBeijingChina
  4. 4.Graduate School of ScienceTohoku UniversitySendaiJapan
  5. 5.Graduate School of Arts and ScienceThe University of TokyoTokyoJapan
  6. 6.Active Fault Research CenterGSJ, AISTTsukubaJapan

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