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Hyperfine Interactions

, Volume 186, Issue 1–3, pp 135–139 | Cite as

Mössbauer study of ancient iron smelting slag in Japan

  • A. Nakanishi
Article
  • 85 Downloads

Abstract

For an investigation of the ancient iron manufacturing technique, a reproducing experiment was carried out by archaeologists, where ancient type of iron smelting furnace was built and iron sand with high titanium contents was used as the raw material. During the operation of furnace, a large amount of slag flowed away from the furnace. In order to investigate the possibility for the estimation about the operative condition of furnace and the raw material, 57Fe Mössbauer spectroscopy was applied for characterizing these slags and it was found that these slags mainly consisted of ferropseudobrookite (FeTi2O5).

Keywords

Iron manufacturing Smelting slag Ferropseudobrookite 

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References

  1. 1.
    Hitachi Metal Ltd.: Tale of the Tatara (2006), which is available at their homepageGoogle Scholar
  2. 2.
    Hagihara, N., Manabe, S., Miono, S., Nakanishi, A.: A discovery of suitable layers for thermoluminescence dating of ancient iron manufacturing furnace to investigate the origin of iron manufacturing in Japan. Quat. Sci. Rev. 20, 987–991 (2001)CrossRefADSGoogle Scholar
  3. 3.
    Nakanishi, A., Kobayashi, T., Miono, S.: Mössbauer study of Japanese ancient iron slag. J. Radioanal. Nucl. Chem. 239, 309–311 (1999)CrossRefGoogle Scholar
  4. 4.
    Babu, D.S.S., Das, D., Sudarshan, M., Reddy, V.R., Chintalapudi, S.N., Majumdar, C.K.: 57Fe Mössbauer studies on natural ilmenites. Ind. J. Pure Appl. Phys. 34, 474–479 (1996)Google Scholar
  5. 5.
    Tanaka, H., Kono, M.: Mössbauer spectra of titanomagnetite: a reappraisal. J. Geomag. Geoelectr. 39, 463–475 (1987)Google Scholar
  6. 6.
    Akimoto, S., Nagata, T., Katsura, T.: The TiFe2O5–Ti2FeO5 solid solution series. Nature 197, 37–38 (1957)CrossRefADSGoogle Scholar
  7. 7.
    Guo, W.Q., Malus, S., Ryan, D.H., Altounian, Z.: Crystal structure and cation distributions in FeTi2O5–Fe2TiO5 solid solution series. J. Phys. Condens. Matter 11, 6337–6346 (1999)CrossRefADSGoogle Scholar
  8. 8.
    Teller, R.G., Antonio, M.R., Grau, A.E., Gueguin, M., Kostiner, E.: Structural analysis of metastable pseudobrookite ferrous titanium oxides with neutron diffraction and Mössbauer spectroscopy. J. Solid State Chem. 88, 334–350 (1990)CrossRefADSGoogle Scholar
  9. 9.
    Virgo, D., Huggins, F.E.: Cation distributions in some compounds with pseudobrookite structure. Carnegie Inst. Wash. Year Book 74, 585–590 (1975)Google Scholar
  10. 10.
    Taylor, L.A., Williams, R.J., McCallister, R.H.: Stability relations of ilmenite and ulvöspinel in the Fe–Ti–O system and application of these date to lunar mineral assemblages. Earth Planet. Sci. Lett. 16, 282–288 (1975)CrossRefADSGoogle Scholar

Copyright information

© Springer Science+Business Media B.V. 2008

Authors and Affiliations

  1. 1.Department of PhysicsShiga University of Medical ScienceShigaJapan

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