Skip to main content
SpringerLink
Log in

119Sn Mössbauer study of nickel–tin anodes for rechargeable lithium-ion batteries

  • Published:
Hyperfine Interactions Aims and scope Submit manuscript

Abstract

119Sn Mössbauer spectrometry has been carried out on Ni–Sn alloys (Ni3Sn LT, Ni3Sn2 LT and Ni3Sn4) and combined with ab initio calculations. Lithium insertion/extraction mechanisms of the most interesting compound (Ni3Sn4) have been studied from 119Sn Mössbauer measurements. The first discharge shows a plateau close to 0.0 V, which can be attributed to the formation of the Li7Sn2 alloy.

This is a preview of subscription content, log in via an institution to check access.

Access this article

Log in via an institution

Price excludes VAT (USA)
Tax calculation will be finalised during checkout.

Instant access to the full article PDF.

Institutional subscriptions

Similar content being viewed by others

References

  1. Sato, K., Noguchi, M., Demachi, A., Oki, N., Endo, M.: Science 264, 556 (1994)

    Article  ADS  Google Scholar 

  2. Dahn, J.R., Zheng, T., Liu, Y., Xue, J.S.: Science 270, 590 (1995)

    Article  ADS  Google Scholar 

  3. Johnson, B.A., White, R.E.: J. Power Sources 70, 48 (1998)

    Article  Google Scholar 

  4. Huggins, R.A.: J. Power Sources 81–82, 13 (1999)

    Article  Google Scholar 

  5. Chouvin, J., Olivier-Fourcade, J., Jumas, J.C., Simon, B., Godiveau, O.: Chem. Phys. Lett. 308, 413 (1999)

    Article  ADS  Google Scholar 

  6. Wachtler, M., Besenhard, J.O., Winter, M.: J. Power Sources 94, 189 (2001)

    Article  Google Scholar 

  7. Winter, M., Besenhard, J.O.: Electrochim. Acta 45, 31 (1999)

    Article  Google Scholar 

  8. Cheng, X.Q., Shi, P.F.: J. Alloys Compd. 391, 241 (2005)

    Article  Google Scholar 

  9. Kepler, K.D., Vaughey, J.T., Thackeray, M.: Electrochem. Solid-State Lett. 2, 307 (1999)

    Article  Google Scholar 

  10. Blaha, P., Schwarz, K., Luitz, J.: WIEN97. Vienna University of Technology (1997) (improved and updated Unix version of the original copyright WIEN code, which was published by P. Blaha, K. Schwarz, P. Sorantin, and S.B. Trickey, Comput. Phys. Commun. 59 (1990) 399)

  11. Lyubimtsev, A.L., Baranov, A.I., Fischer, A., Kloo, L., Popovkin, B.A.: J. Alloys Compd. 340, 167 (2002)

    Article  Google Scholar 

  12. Fjellvag, H., Kjekshus, A.: Acta Chem. Scand., A 40, 23 (1986)

    Article  Google Scholar 

  13. Jeitschko, W., Jaberg, B.: Acta Crystallogr., B 38, 598 (1982)

    Article  Google Scholar 

  14. Mildenberger, R., Venskutonis, A., Aubertin, F., Breme, J., Schwitzgebel, G.: Hyperfine Interact. 112, 151 (1998)

    Article  ADS  Google Scholar 

  15. Lippens, P.E., Olivier-Fourcade, J., Jumas, J.C.: Hyperfine Interact. 126, 137 (2000)

    Article  ADS  Google Scholar 

  16. Lippens, P.E., Jumas, J.C., Olivier-Fourcade, J.: Hyperfine Interact. 156/157, 327 (2004)

    Article  ADS  Google Scholar 

  17. Robert, F., Lippens, P.E., Fourcade, R., Jumas, J.C., Gillot, F., Morcrette, M., Tarascon, J.M.: Hyperfine Interact. (2006, this volume)

  18. Bahgat, A.A.: Phys. Status Solidi. B 97, K129 (1980)

    Google Scholar 

Download references

Author information

Authors and Affiliations

  1. Laboratoire des Agrégats Moléculaires et Matériaux Inorganiques (CNRS UMR 5072), Université Montpellier II, CC 015, Place E. Bataillon, 34095, Montpellier cedex 5, France

    S. Naille, P. E. Lippens, F. Morato & J. Olivier-Fourcade

Authors
  1. S. Naille
    View author publications

    You can also search for this author in PubMed Google Scholar

  2. P. E. Lippens
    View author publications

    You can also search for this author in PubMed Google Scholar

  3. F. Morato
    View author publications

    You can also search for this author in PubMed Google Scholar

  4. J. Olivier-Fourcade
    View author publications

    You can also search for this author in PubMed Google Scholar

Corresponding author

Correspondence to S. Naille.

Rights and permissions

Reprints and permissions

About this article

Cite this article

Naille, S., Lippens, P.E., Morato, F. et al. 119Sn Mössbauer study of nickel–tin anodes for rechargeable lithium-ion batteries. Hyperfine Interact 167, 785–790 (2006). https://doi.org/10.1007/s10751-006-9357-7

Download citation

  • Published:

  • Issue Date:

  • DOI: https://doi.org/10.1007/s10751-006-9357-7

Key words

Search

Navigation