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Hyperfine Interactions

, Volume 166, Issue 1–4, pp 465–468 | Cite as

Metallosupramolecular coordination polyelectrolytes investigated by Mössbauer spectroscopy

  • A. Lindner
  • M. Menzel
  • F. Renz
  • D. G. Kurth
  • A. F. Thünemann
Article

Abstract

Metallosupramolecular coordination polyelectrolytes (MEPEs) based on rigid and flexible ditopic bis-terpyridine ligands and Fe(II) ions are investigated by Mössbauer spectroscopy. We demonstrate the influence of mechanical stress induced by grinding on the structure of MEPE as well as the ability of MEPE to self-repair through recrystallisation.

Key words

metallosupramolecular coordination polyelectrolyte bis-terpyridine Mössbauer spectroscopy supramolecular chemistry 

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Copyright information

© Springer Science+Business Media, Inc. 2006

Authors and Affiliations

  • A. Lindner
    • 1
  • M. Menzel
    • 2
  • F. Renz
    • 4
  • D. G. Kurth
    • 1
    • 3
  • A. F. Thünemann
    • 2
  1. 1.Max-Planck-Institute of Colloids and InterfacesPotsdamGermany
  2. 2.Federal Institute for Materials Research and Testing (BAM)BerlinGermany
  3. 3.National Institute for Materials ScienceTsukubaJapan
  4. 4.Johannes Gutenberg-Universität MainzMainzGermany

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