Abstract
The final iron product of the 60-Co gamma radiolysis of lithium trisoxalatoferrate(III) pentahydrate has been identified by Mössbauer spectroscopy as FeC2O4.2H2O. Quantitative chemical and Mössbauer analyses show that the radiolytic decomposition proceeds as a first order reaction as a function of the absorbed dose. Chemical calibration of the relative peaks areas of the two iron species indicates that the corresponding Lamb–Mössbauer factors ratio is unaffected by the radiolysis.
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Ladriere, J., Senterre, V. Mössbauer study on the gamma radiolysis of lithium trisoxalatoferrate (III) pentahydrate. Hyperfine Interact 166, 443–447 (2005). https://doi.org/10.1007/s10751-006-9306-5
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DOI: https://doi.org/10.1007/s10751-006-9306-5