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Study on charge transfer interaction and valence state of layered perovskite-type mixed valence complex [NH3(CH2) n NH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7, 8), by means of 197Au Mössbauer spectroscopy

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Abstract

Cs2[AuI X 2][AuIII X 4](X = Cl, Br, and I) is well known for the three-dimensional perovskite-type gold mixed valence system. Recently, layered perovskite-type gold mixed valence complexes, [NH3(CH2) n NH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7 and 8), have been synthesized. We have investigated the relationship between the structural dimensionality and the AuI–AuIII charge transfer interaction for Cs2[AuII2][AuIIII4] and [NH3(CH2) n NH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7 and 8) by means of 197Au Mössbauer spectroscopy.

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Authors and Affiliations

  1. Graduate School of Arts and Sciences, The University of Tokyo, Tokyo, 153-8902, Japan

    Kazuhiro Ikeda & Norimichi Kojima

  2. Kyoto University Research Reactor Institute, Osaka, 590-0494, Japan

    Yasuhiro Kobayashi & Makoto Seto

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  1. Kazuhiro Ikeda
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  2. Norimichi Kojima
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  3. Yasuhiro Kobayashi
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  4. Makoto Seto
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Correspondence to Kazuhiro Ikeda.

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Ikeda, K., Kojima, N., Kobayashi, Y. et al. Study on charge transfer interaction and valence state of layered perovskite-type mixed valence complex [NH3(CH2) n NH3]2[(AuII2)(AuIIII4)(I3)2] (n = 7, 8), by means of 197Au Mössbauer spectroscopy. Hyperfine Interact 166, 403–407 (2005). https://doi.org/10.1007/s10751-006-9300-y

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  • DOI: https://doi.org/10.1007/s10751-006-9300-y

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